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1-Azidohexane

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Identification
Molecular formula
C6H13N3
CAS number
6388-89-8
IUPAC name
1-azidohexane
State
State

At room temperature, 1-Azidohexane is in a liquid state.

Melting point (Celsius)
-57.50
Melting point (Kelvin)
215.70
Boiling point (Celsius)
150.00
Boiling point (Kelvin)
423.00
General information
Molecular weight
127.19g/mol
Molar mass
127.1710g/mol
Density
0.8950g/cm3
Appearence

1-Azidohexane is typically a colorless liquid. Azido compounds often have distinct odors and should be handled with caution due to their potential explosiveness.

Comment on solubility

Solubility of 1-azidohexane

1-azidohexane, represented by the formula C6H14N2, exhibits solubility characteristics influenced by its unique functional group and hydrocarbon chain. Understanding its solubility can be key for various applications in synthetic chemistry and can be summarized as follows:

  • Polarity: The azido functional group (-N≡N) introduces a certain level of polarity, which can enhance solubility in polar solvents.
  • Hydrophobic Chain: The hexane backbone is predominantly hydrophobic, meaning 1-azidohexane is less soluble in water, a polar solvent, due to its nonpolar components.
  • Solvent Compatibility: 1-azidohexane tends to be more soluble in organic solvents, such as:
    • Diethyl ether
    • Chloroform
    • Benzene
    • Acetone
  • Temperature Dependence: The solubility can also vary with changes in temperature, often increasing with elevated temperatures for organic solvents.

In summary, while 1-azidohexane shows limited solubility in water, its compatibility with several organic solvents makes it versatile in synthetic applications. Thus, for practical purposes, it is crucial to choose the appropriate solvent based on its solubility profile to optimize reactions involving this compound.

Interesting facts

Interesting Facts About 1-Azidohexane

1-Azidohexane is a fascinating organic compound that belongs to the family of azides, recognized for their unique structural properties and reactivity. Here are some intriguing aspects of 1-azidohexane:

  • Structure and Composition: 1-Azidohexane features a linear carbon chain with a terminal azide group. This unique structure plays a significant role in its chemical behavior and reactivity.
  • Reactivity: Azides are known for their ability to undergo a variety of chemical reactions, especially when subjected to heat or shock. The azide functional group is particularly interesting due to its propensity for nucleophilic substitution reactions.
  • Applications: 1-Azidohexane and other azides have important applications in organic synthesis and materials science. They are used in the preparation of explosives, pharmaceuticals, and as intermediates in organic reactions.
  • Safety Concerns: Despite their useful applications, azides can be highly reactive and potentially hazardous. Proper safety precautions—including the use of protective equipment and controlled environments—are essential when handling 1-azidohexane.
  • Synthetic Routes: The synthesis of 1-azidohexane typically involves the displacement of a halogen atom in a halogenated derivative of hexane, showcasing the versatility of organic synthesis techniques.

As with many azides, 1-azidohexane serves as an excellent example of the intersection between innovative chemistry and practical applications, illustrating both the beauty and complexity of organic compounds. Its diverse utility and reactivity continue to draw the interest of chemists and researchers alike.

Synonyms
1-Azidohexane
Hexyl azide
6926-45-0
HEXANE, 1-AZIDO-
N-Hexyl azide
1-azido-hexane
Hexylazide
CCRIS 9469
SCHEMBL13569662
DTXSID90219326
GAA92645
AKOS010633573
BP-29655
EN300-152403
F1901-3141