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1-nitro-4-(4-nitrophenoxy)benzene

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Identification
Molecular formula
C12H8N2O5
CAS number
3139-02-0
IUPAC name
1-nitro-4-(4-nitrophenoxy)benzene
State
State

At room temperature, 1-nitro-4-(4-nitrophenoxy)benzene is a solid. It is generally stable under normal conditions but should be kept away from strong reducing agents to prevent any undesired reactions.

Melting point (Celsius)
145.00
Melting point (Kelvin)
418.10
Boiling point (Celsius)
407.50
Boiling point (Kelvin)
680.70
General information
Molecular weight
276.21g/mol
Molar mass
276.2250g/mol
Density
1.5400g/cm3
Appearence

1-Nitro-4-(4-nitrophenoxy)benzene generally appears as an off-white to light yellow crystalline solid. It may also appear as powder or small flakes, depending on the method of preparation and handling conditions. The compound is typically used in research settings rather than in general industrial applications.

Comment on solubility

Solubility of 1-nitro-4-(4-nitrophenoxy)benzene

1-nitro-4-(4-nitrophenoxy)benzene, a compound characterized by its unique nitrophenyl structure, exhibits interesting solubility properties that are worth discussing.

General Solubility Characteristics:

This compound is known to have limited solubility in water due to the following reasons:

  • Hydrophobic Nature: The extensive aromatic rings contribute to a substantial hydrophobic character, inhibiting solvation in polar solvents such as water.
  • Polarity: The presence of nitro groups, while polar, does not sufficiently compensate for the overall non-polar character of the compound.
  • Intermolecular Interactions: Strong π-π stacking interactions between the aromatic rings may lead to aggregation, further reducing solubility.

Solubility in Organic Solvents:

In contrast, 1-nitro-4-(4-nitrophenoxy)benzene is considerably more soluble in non-polar and moderately polar organic solvents, including:

  • Dimethyl sulfoxide (DMSO)
  • Acetone
  • Toluene

This enhanced solubility can be attributed to the ability of organic solvents to solvating organic compounds effectively through van der Waals forces and dipole interactions.

Conclusion:

In summary, understanding the solubility of 1-nitro-4-(4-nitrophenoxy)benzene provides critical insights into its applications in various chemical processes and reactions. While its limited solubility in water poses challenges, its behavior in organic solvents opens up numerous opportunities for its use in synthetic chemistry.

Interesting facts

1-Nitro-4-(4-nitrophenoxy)benzene: A Unique Chemical Compound

1-Nitro-4-(4-nitrophenoxy)benzene is an intriguing compound that has garnered interest in the fields of chemistry and materials science. Here are some fascinating aspects of this compound:

  • Structure and Functional Groups: This compound features a benzene ring substituted with nitro groups, which are known for their electron-withdrawing ability, and a phenoxy group. The presence of these functional groups significantly influences the compound's chemical reactivity and properties.
  • Applications in Chemistry: Compounds like 1-nitro-4-(4-nitrophenoxy)benzene are often used in the synthesis of more complex molecules, especially in the development of pharmaceuticals and agrochemicals. They can serve as intermediates in organic synthesis.
  • Potential Uses: Due to its nitro groups, this compound may have potential applications in the field of explosives or as a precursor in dye synthesis. In particular, nitrophenyl compounds are instrumental in the manufacturing of various dyes and pigments.
  • Environmental Concerns: As a nitroaromatic compound, care must be taken when working with 1-nitro-4-(4-nitrophenoxy)benzene. Nitro compounds can be toxic and may pose ecological risks, making it essential to handle them with caution and awareness of their environmental impact.
  • Research Frontier: The exploration of nitro-substituted aromatic compounds continues to be a vibrant area of research. Scientists are investigating their electronic properties and applications in material sciences, including conducting polymers and organic photovoltaics.

In conclusion, 1-nitro-4-(4-nitrophenoxy)benzene is more than just a chemical compound; it holds the promise of innovation in various scientific fields. As researchers delve deeper into its properties and applications, we can expect to uncover further insights into this remarkable substance.

Synonyms
4,4'-Dinitrodiphenyl ether
101-63-3
1-Nitro-4-(4-nitrophenoxy)benzene
p-Nitrophenyl ether
Benzene, 1,1'-oxybis[4-nitro-
Bis(4-nitrophenyl) ether
4,4'-Oxybis(nitrobenzene)
Di-4-nitrophenyl ether
Ether, bis(p-nitrophenyl)
p,p'-Dinitrodiphenyl ether
Oxybis(4-nitrobenzene)
4,4'-Dinitrodiphenyl oxide
Ether, bis(4-nitrophenyl)
Bis(4-nitrophenyl)ether
1,1'-Oxybis(4-nitrobenzene)
Bis(p-nitrophenyl)ether
Bis(p-nitrophenyl) ether
NSC 8740
Oxybis[4-nitrobenzene]
Benzene, 1,1'-oxybis(4-nitro-
EINECS 202-961-3
T852Y5UXCE
4-nitrophenyl ether
BRN 2058965
DTXSID0026676
AI3-08831
NSC-8740
DTXCID306676
4-06-00-01290 (Beilstein Handbook Reference)
BENZENE, 1,1'-OXYBIS(4-NITRO-)
1,1'-Oxybis[4-nitrobenzene]
Benzene,1,1'-oxybis[4-nitro-
UNII-T852Y5UXCE
4,4/'-Dinitrodiphenyl ether
MFCD00059182
Bis-(p-nitrophenyl)ether
Oprea1_307506
4,4\'-Dinitrodiphenyl Ether
Benzene,1'-oxybis[4-nitro-
SCHEMBL134332
CHEMBL2270117
NSC8740
4,4'-dinitrodiphenylA currencyther
4,4'-Dinitrodiphenyl ether, 96%
Tox21_200432
1-nitro-4-(4-nitro-phenoxy)-benzene
AKOS000121174
1-Nitro-4-(4-nitrophenoxy)benzene #
UPCMLD0ENAT5894417:001
NCGC00248611-01
NCGC00257986-01
BS-42099
CAS-101-63-3
CS-0215630
D0832
EU-0067037
NS00001266
EN300-26781
D89725
Q27289802
Z31207505
202-961-3