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Chloramine-T

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Identification
Molecular formula
C7H7Cl4NO2S
CAS number
127-65-1
IUPAC name
1,8,9,10,11,11-hexachloro-4-oxido-5-aza-4-azoniatetracyclo[6.2.1.13,6.02,7]dodeca-4,9-diene
State
State

Chloramine-T is typically found as a solid at room temperature. It is stable under ordinary conditions but decomposes in the presence of light and moisture, releasing chlorine gas.

Melting point (Celsius)
176.00
Melting point (Kelvin)
449.15
Boiling point (Celsius)
280.00
Boiling point (Kelvin)
553.15
General information
Molecular weight
227.54g/mol
Molar mass
227.5390g/mol
Density
1.8860g/cm3
Appearence

Chloramine-T is a white to off-white crystalline powder. It is known for its strong chlorine-like odor due to the presence of chlorinated compounds. When it comes into contact with moisture, it may emit chlorine gas.

Comment on solubility

Solubility of 1,8,9,10,11,11-Hexachloro-4-oxido-5-aza-4-azoniatetracyclo[6.2.1.13,6.02,7]dodeca-4,9-diene

The solubility of 1,8,9,10,11,11-hexachloro-4-oxido-5-aza-4-azoniatetracyclo[6.2.1.13,6.02,7]dodeca-4,9-diene is a notable aspect that often encounters attention in various chemical contexts. Factors influencing its solubility include:

  • Polarity: The presence of multiple chlorine atoms and nitrogen in the molecular structure can enhance polarity, potentially affecting solubility in polar solvents.
  • Hydrophobic and hydrophilic regions: The balance between hydrophobic (due to the chlorine substituents) and hydrophilic regions (due to the azonium and oxido groups) can affect its solubility in aqueous environments.
  • Temperature: As with many chemical compounds, temperature variations can lead to differences in solubility, often increasing with higher temperatures.

In general, one might expect that this compound would show limited solubility in water due to its complex and heavily halogenated structure. However, it may demonstrate greater solubility in organic solvents, particularly those that can interact favorably with its ionic and polar characteristics.

In summary, solubility can be summarized as:

  • If dissolved in nonpolar solvents: Likely to be more soluble.
  • If placed in polar solvents: Expect limited solubility.

As always, empirical tests provide the most reliable data regarding solubility in specific substances, making laboratory studies critical for thorough characterization.

Interesting facts

Interesting Facts about 1,8,9,10,11,11-Hexachloro-4-oxido-5-aza-4-azoniatetracyclo[6.2.1.13,6.02,7]dodeca-4,9-diene

The compound 1,8,9,10,11,11-hexachloro-4-oxido-5-aza-4-azoniatetracyclo[6.2.1.13,6.02,7]dodeca-4,9-diene is a fascinating member of the broader class of chemical compounds known for their unique structural attributes and potential applications.

Structural Complexity

This compound is characterized by a complex framework, which includes:

  • Hexachloro Substitution: The presence of six chlorine atoms contributes to its reactivity and stability.
  • Aza and Azo Functions: The incorporation of nitrogen makes this molecule a part of the azonium family, lending to its intriguing chemical behavior.
  • Tetracyclic Ring System: The multiple interlinked cyclic structures give it unique spatial properties that can influence its interactions with other molecules.

Chemical and Biological Significance

The structural features of this compound are not just academically interesting; they also suggest potential in various fields:

  • Medicinal Chemistry: Compounds with chlorinated and azole functionalities are often explored for their antibiotic and antitumor properties.
  • Material Science: The stability imparted by halogen atoms can be crucial in developing novel materials and polymers.
  • Environmental Chemistry: Understanding the behavior of such chlorinated compounds aids in assessing their environmental impact and biocompatibility.

Unexpected Aspects

In addition to their chemical viability, compounds like this one often pose unexpected challenges:

  • Toxicity: The chlorinated nature raises concerns, as many such compounds have been found to be harmful to biological systems.
  • Regulatory Scrutiny: Due to their potential environmental impact, compounds with such structures are subject to rigorous regulatory evaluations.

In summary, 1,8,9,10,11,11-hexachloro-4-oxido-5-aza-4-azoniatetracyclo[6.2.1.13,6.02,7]dodeca-4,9-diene exemplifies the incredible diversity found within chemical compounds. Its complex structure holds the key to both future scientific explorations and the practical implications that come with studying such intricate molecules.

Synonyms
5,6,7,8,9,9-Hexachloro-1,4,4a,5,8,8a-hexahydro-1,4:5,8-dimethanophthalazine 2-oxide
14458-95-8
Shell SD-3450
SD 3450
ENT 25582
BRN 0042225
AI3-25582
1,4:5,8-Dimethanophthalazine, 5,6,7,8,9,9a-hexachloro-1,4,4a,5,8,8a-hexahydro-, 2-oxide
4-23-00-01184 (Beilstein Handbook Reference)
1,4:5,8-Dimethanophthalazine, 5,6,7,8,9,9-hexachloro-1,4,4a,5,8,8a-hexahydro-, 2-oxide
1,4:5,8-Dimethanophthalazine, 5,6,7,8,9,9-hexachloro-1,4,4a,5,8,8a-hexahydro-, oxide