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4-Chlorophenyl-1,3-dithiolane

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Identification
Molecular formula
C9H9ClS2
CAS number
16264-05-0
IUPAC name
2-(4-chlorophenyl)-1,3-dithiolane
State
State

At room temperature, 2-(4-Chlorophenyl)-1,3-dithiolane is in a solid state. It is generally handled as a solid compound with a crystalline appearance.

Melting point (Celsius)
67.50
Melting point (Kelvin)
340.65
Boiling point (Celsius)
252.00
Boiling point (Kelvin)
525.15
General information
Molecular weight
204.75g/mol
Molar mass
204.7340g/mol
Density
1.3091g/cm3
Appearence

2-(4-Chlorophenyl)-1,3-dithiolane typically appears as a crystalline solid. Its color may range from white to off-white or yellowish, depending on its purity and specific form.

Comment on solubility

Solubility of 2-(4-chlorophenyl)-1,3-dithiolane

The compound 2-(4-chlorophenyl)-1,3-dithiolane exhibits unique solubility characteristics that can be influenced by its structural properties.

Solubility Characteristics:

  • Polar vs. Non-Polar Solvents: This compound is likely soluble in polar organic solvents such as ethanol and acetone due to its polar dithiolane group, which can engage in hydrogen bonding.
  • Water Solubility: It is generally expected to be insoluble in water because of its hydrophobic aromatic ring, indicating a preference for non-polar environments.
  • Heating Effect: Upon increasing temperature, solubility may enhance, particularly in organic solvents, showcasing the influence of kinetic energy on solute-solvent interactions.
  • Concentration Considerations: At high concentrations, precipitation can occur, which is a common phenomenon observed with compounds that have limited solubility.

In summary, while 2-(4-chlorophenyl)-1,3-dithiolane showcases better solubility in polar organic solvents, it remains largely insoluble in water. Understanding these solubility properties is essential for applications involving this compound, be it in synthesis or formulation processes.

Interesting facts

Interesting Facts about 2-(4-chlorophenyl)-1,3-dithiolane

2-(4-chlorophenyl)-1,3-dithiolane is a fascinating compound that has garnered attention in various fields of chemistry, particularly in the study of organosulfur compounds. Here are some intriguing aspects of this compound:

  • Structural Composition: The compound contains a dithiolane ring, which is a five-membered cyclic structure featuring two sulfur atoms. This unique arrangement contributes to its reactivity and potential applications.
  • Substituent Impact: The presence of the 4-chlorophenyl substituent significantly influences the compound's chemical properties. Chlorine, being an electronegative atom, can enhance the compound's reactivity and alter its interaction with other molecules.
  • Reactivity and Applications: Compounds containing dithiolane rings are studied for their ability to undergo various chemical reactions, including nucleophilic substitutions. They are also of interest in medicinal chemistry for potential therapeutic applications.
  • Environmental and Synthesis Insight: The synthesis of 2-(4-chlorophenyl)-1,3-dithiolane can provide insights into environmentally friendly synthetic methods, especially in the context of green chemistry initiatives.
  • Potential Utility: Due to its unique structure, this compound may serve as an intermediate in the synthesis of more complex organic molecules, opening doors for innovation in pharmaceuticals and agrochemicals.

As with many organosulfur compounds, the study of 2-(4-chlorophenyl)-1,3-dithiolane emphasizes the balance of reactivity and stability, making it a noteworthy subject for both scientists and chemistry students. Its intriguing combination of sulfur and aromatic systems allows researchers to explore new horizons in material science and medicinal applications.

Synonyms
1,3-DITHIOLANE, 2-(p-CHLOROPHENYL)-
23229-32-5
2-(p-Chlorophenyl)-1,3-dithiolane
2-(4-Chlorophenyl)-1,3-dithiolane
DTXSID60177803
BRN 0141806
1,3-Dithiolane, 2-(4-chlorophenyl)-
AI3-22822
RefChem:1061193
p-chlorophenyl-1,3-dithiolane
SCHEMBL11612852
OCPZVXIFXYBOHG-UHFFFAOYSA-
DTXCID80100294
OCPZVXIFXYBOHG-UHFFFAOYSA-N
2-(4-Chlorophenyl)-1,3-dithiolane #
2-[4-Chlorophenyl]-1,3-dithiacyclopentane
InChI=1/C9H9ClS2/c10-8-3-1-7(2-4-8)9-11-5-6-12-9/h1-4,9H,5-6H2