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2-Methoxy-2-thioxo-4H-1,3,2λ5-benzodioxaphosphinine

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Identification
Molecular formula
C8H5O3PS
CAS number
n/a
IUPAC name
2-methoxy-2-thioxo-4H-1,3,2lambda5-benzodioxaphosphinine
State
State

At room temperature, 2-Methoxy-2-thioxo-4H-1,3,2λ5-benzodioxaphosphinine is typically a solid.

Melting point (Celsius)
67.00
Melting point (Kelvin)
340.15
Boiling point (Celsius)
235.00
Boiling point (Kelvin)
508.00
General information
Molecular weight
218.18g/mol
Molar mass
218.1840g/mol
Density
1.3803g/cm3
Appearence

The appearance of this compound has not been specifically documented in literature. As it is a phosphinine-based compound, it might be expected to be a crystalline solid. Specific color or crystalline form details would require experimental confirmation.

Comment on solubility

Solubility of 2-methoxy-2-thioxo-4H-1,3,2λ5-benzodioxaphosphinine

The solubility profile of 2-methoxy-2-thioxo-4H-1,3,2λ5-benzodioxaphosphinine is intriguing and can be attributed to its unique chemical structure. This compound exhibits specific solubility characteristics that warrant a closer look:

  • Polarity: The presence of the methoxy group may introduce a level of polarity, affecting its overall solubility in polar solvents.
  • Solvent Compatibility: This compound is generally more soluble in organic solvents such as ethanol and acetone, while its solubility in water is likely to be limited due to hydrophobic characteristics.
  • Influence of pH: Changes in pH can significantly alter the solubility, especially if protonation or deprotonation occurs.
  • Complex Formation: It may form complexes with certain metal ions or other organic molecules, which can enhance solubility in certain cases.

In summary, while 2-methoxy-2-thioxo-4H-1,3,2λ5-benzodioxaphosphinine demonstrates interesting solubility attributes, experimental conditions must be optimized to fully understand its behavior in different solvents. The intricate balance of polarity, solvent interactions, and molecular structure play pivotal roles in determining its solubility.

Interesting facts

Interesting Facts About 2-Methoxy-2-thioxo-4H-1,3,2lambda5-benzodioxaphosphinine

2-Methoxy-2-thioxo-4H-1,3,2lambda5-benzodioxaphosphinine is a fascinating compound that combines elements of organic and inorganic chemistry, particularly due to its unique phosphorus-containing structure. Here are some intriguing insights about this compound:

  • Hybrid Structure: This compound features a heterocyclic ring with phosphorus atoms, which is quite rare in the realm of organic chemistry. It represents an intersection of traditional organic chemistry and the lesser-explored domain of organophosphorous chemistry.
  • Potential Applications: Compounds similar to this one are often investigated for their potential use as pharmaceuticals or agricultural chemicals. Their ability to interact with biological systems can lead to discoveries of new drug candidates.
  • Reactive Nature: The thioxo group (-C=S) and the methoxy group (-OCH3) can provide unique reactivity patterns, making this compound a subject for study in synthetic organic chemistry.
  • Research Importance: Compounds like this have garnered attention in material science, particularly in the development of optical materials and catalysts, hinting at their versatility beyond traditional uses.
  • Phosphorus Chemistry: The presence of phosphorus in its structure introduces unique aspects of reactivity and bonding, which are critical for understanding how such compounds can participate in various chemical processes.

With a structure that combines the elements of both benzene-like rings and phosphorus, 2-methoxy-2-thioxo-4H-1,3,2lambda5-benzodioxaphosphinine stands as a testament to the creative possibilities within synthetic chemistry. As scientists explore its properties and potential, it paves the way for deeper discussions about the role of phosphorus in organic compounds.

Synonyms
Dioxabenzofos
Salithion
3811-49-2
Dioxabenzophos
Salithion-sumitomo
Fenphosphorin
Dioxabenzofos [BSI:ISO]
CCRIS 9111
4H-1,3,2-Benzodioxaphosphorin, 2-methoxy-, 2-sulfide
EINECS 223-292-3
6ZWK96BZW6
BRN 1875270
FENFOSPHORIN
2-Methoxy-4H-1,3,2-benzodioxaphosphorin 2-sulfide
2-Methoxy-4H-1,2,3-benzodioxaphosphorine-2-sulfide
AI3-27204
Phosphorothioic acid, cyclic O,O-(methylene-o-phenylene) O-methyl ester
DIOXABENZOFOS [ISO]
2-methoxy-4H-1,3,2-benzodioxaphosphorin-2-sulfide
2-Methoxy-4H-1,3,2-benzodioxaphosphorin 2-sulphide
2-Methoxy-4H-benzo-1,3,2-dioxaphosphorin 2-sulphide
4H-(1.3.2)Benzodioxaphosphorine, 2-methoxy-, 2-sulfide
DTXSID7041885
2-Methoxy-4H-1,3,2-lambda-5-benzodioxaphosphinine 2-sulfide
2-Methoxy-4H-1,3,2-lambda-5-benzodioxaphosphinine 2-sulphide
Cyclic O,O-(methylene-o-phenylene) phosporothioate O-methyl ester
SALIGENIN CYCLIC METHYL PHOSPHOROTHIONAT
Phosphorothioic acid, O-methyl ester, cyclic O,O-ester with o-hydroxybenzyl alcohol
2-METHOXY-4H-1,3,2-BENZODIOXAPHOSPHOLIN-2-SULFIDE
(RS)-2-METHOXY-4H-1,3,2.DELTA.5-BENZODIOXAPHOSPHININE 2-SULFIDE
(RS)-2-METHOXY-4H-1,3,2.DELTA.5-BENZODIOXAPHOSPHORINE 2-SULFIDE
(RS)-2-METHOXY-4H-1,3,2.LAMBDA.(SUP 5)-BENZODIOXAPHOSPHININE 2-SULFIDE
BENZYL ALCOHOL, O-HYDROXY-, CYCLIC O,O-ESTER WITH O-METHYL PHOSPHOROTHIOATE
(+-)-DIOXABENZOFOS
DIOXABENZOFOS, (+-)-
DTXCID5021885
2-Methoxy-4H-1,3,2-benzodioxaphosphorin 2-sulfide (9CI)
Cyclic O,O-(methylene-o-phenylene) phosporothioate O-methyl ester (8CI)
(RS)-2-METHOXY-4H-1,3,2DELTA5-BENZODIOXAPHOSPHININE 2-SULFIDE
(RS)-2-METHOXY-4H-1,3,2DELTA5-BENZODIOXAPHOSPHORINE 2-SULFIDE
(RS)-2-METHOXY-4H-1,3,2LAMBDA(SUP 5)-BENZODIOXAPHOSPHININE 2-SULFIDE
CHEBI:82120
K-9
Dioxabenzofos; Salithion
2-methoxy-2-sulfanylidene-4H-1,3,2lambda5-benzodioxaphosphinine
90293-16-6
2-methoxy-4H-benzo[d][1,3,2]dioxaphosphinine 2-sulfide
(R)-Salithion
(S)-Salithion
(R)-(+)-Salithion
UNII-6ZWK96BZW6
90293-10-0
Dioxabenzofos 10 microg/mL in Cyclohexane
SCHEMBL83406
(+/-)-DIOXABENZOFOS
CHEMBL226967
OUNSASXJZHBGAI-UHFFFAOYSA-
DIOXABENZOFOS, (+/-)-
AKOS040744712
Saligenin cyclic methyl phosphorothionate
Dioxabenzofos 100 microg/mL in Acetonitrile
NS00022125
C18981
Dioxabenzofos, PESTANAL(R), analytical standard
Q27155757
2-Methoxy-4H-1,3,2-benzodioxaphosphinine 2-sulfide #
o-methyl cyclic o,o-(methylene-o-phenylene)phosphorothioate
4H-1,3,2-Benzodioxaphosphorin, 2-methoxy-, 2-sulfide, (R)-
4H-1,3,2-Benzodioxaphosphorin, 2-methoxy-, 2-sulfide, (S)-
8-methoxy-8-sulfanylidene-7,9-dioxa-8$l^{5}-phosphabicyclo[4.4.0]deca-1,3,5-trie
InChI=1/C8H9O3PS/c1-9-12(13)10-6-7-4-2-3-5-8(7)11-12/h2-5H,6H2,1H3