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2,2-Diethyl-1,3-dithiolane

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Identification
Molecular formula
C7H14S2
CAS number
22747-62-2
IUPAC name
2,2-diethyl-1,3-dithiolane
State
State

At room temperature, 2,2-diethyl-1,3-dithiolane is found in a liquid state, making it fluid and capable of being poured. Its relatively low melting point means it remains liquid under a wide range of everyday conditions.

Melting point (Celsius)
-70.00
Melting point (Kelvin)
203.15
Boiling point (Celsius)
215.00
Boiling point (Kelvin)
488.15
General information
Molecular weight
148.29g/mol
Molar mass
148.2880g/mol
Density
0.9690g/cm3
Appearence

2,2-Diethyl-1,3-dithiolane is a liquid compound that is colorless to very pale yellow in appearance. Its liquid state is relatively clear and it typically has a characteristic sulfide odor.

Comment on solubility

Solubility of 2,2-Diethyl-1,3-dithiolane

2,2-Diethyl-1,3-dithiolane, with its unique structure, presents interesting solubility characteristics. Understanding its solubility behavior can be crucial for various applications in organic synthesis and materials science.

General Solubility Trends

This compound's solubility can be influenced by several factors:

  • Polarity: Due to the presence of dithiolane functionality, which features sulfur atoms, the compound has a degree of polarity.
  • Hydrophobic Characteristics: The ethyl groups impart a hydrocarbon nature, likely rendering it more soluble in organic solvents.
  • Solvent Choices: 2,2-Diethyl-1,3-dithiolane is expected to be soluble in non-polar to moderately polar solvents, such as:
    • Hexane
    • Toluene
    • Chloroform

Solubility Insights

While specific solubility data may be limited, the general behavior of such thiol-enriched compounds points towards higher solubility in organic solvents compared to water. This is primarily due to:

  • Lower interaction with water due to non-polar ethyl groups.
  • Chain flexibility and the presence of sulfur, which influences solute-solvent interactions.

In practical applications, the solubility profile of 2,2-diethyl-1,3-dithiolane can be summarized as follows:

  1. Highly soluble in organic solvents.
  2. Poorly soluble in water.

Thus, for researchers and practitioners, it is essential to consider these solubility aspects when working with 2,2-diethyl-1,3-dithiolane in various chemical processes.

Interesting facts

Interesting Facts about 2,2-Diethyl-1,3-Dithiolane

2,2-Diethyl-1,3-dithiolane is a fascinating compound that belongs to the category of dithiolanes, which are characterized by their sulfur-containing ring structure. Found in various chemical applications, this compound is notable for several reasons:

  • Sulfur Richness: The presence of sulfur atoms in its structure grants this compound unique reactivity and properties that might differ from similar compounds lacking sulfur.
  • Regioselectivity: The specific arrangement of ethyl groups allows for interesting regioselective reactions, making this compound a point of interest for synthetic chemistry.
  • Applications in Synthesis: 2,2-Diethyl-1,3-dithiolane can serve as a useful building block in organic synthesis. Its reactivity can be exploited in creating other complex molecular architectures.
  • Potential in Material Science: Research is ongoing into the applications of dithiolanes in developing new materials, particularly in electronics and nanotechnology.
  • Environmental Relevance: Compounds like 2,2-Diethyl-1,3-dithiolane may play a role in the study of environmental chemistry, particularly in understanding sulfur pathways in nature.

One of the compelling aspects of studying compounds like 2,2-Diethyl-1,3-dithiolane is how they challenge our understanding of chemical reactivity and stability. As Henry Ford famously said, "The only source of knowledge is experience." Thus, experimenting with and learning from such compounds can lead to innovative discoveries and applications that push the boundaries of current chemical knowledge.

Whether in the realm of organic synthesis or material science, 2,2-Diethyl-1,3-dithiolane exemplifies the beauty of chemistry, highlighting how simple changes in structure can lead to profound differences in behavior and application.

Synonyms
2,2-Diethyl-1,3-dithiolane
BRN 1361773
1,3-DITHIOLANE, 2,2-DIETHYL-
26733-25-5
DTXSID80181245
5-19-01-00109 (Beilstein Handbook Reference)
RefChem:219162
DTXCID90103736
FMCABCBXHDYTHA-UHFFFAOYSA-N
SCHEMBL2180808
AKOS024328880