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Solketal

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Identification
Molecular formula
C7H14O3
CAS number
100-79-8
IUPAC name
(2,2-dimethyl-1,3-dioxolan-4-yl)methanol
State
State

At room temperature, Solketal is a liquid. However, it is known to crystallize or solidify slightly below room temperature.

Melting point (Celsius)
35.00
Melting point (Kelvin)
308.15
Boiling point (Celsius)
188.00
Boiling point (Kelvin)
461.15
General information
Molecular weight
132.16g/mol
Molar mass
132.1600g/mol
Density
1.0731g/cm3
Appearence

Solketal is a colorless liquid that may appear as a slightly viscous substance. It is often described as having a faint, sweet odor.

Comment on solubility

Solubility of (2,2-Dimethyl-1,3-dioxolan-4-yl)methanol

The solubility of the compound (2,2-dimethyl-1,3-dioxolan-4-yl)methanol exhibits interesting characteristics due to its unique structure containing both dioxolane and alcohol functional groups. This compound is likely to be soluble in polar solvents and shows variations in solubility based on the following factors:

  • Polarity: The presence of the hydroxyl (-OH) group significantly enhances its solubility in water.
  • Hydrogen Bonding: The ability to form hydrogen bonds with water or other polar solvents contributes to its solubility.
  • Alkyl Substituents: The dimethyl groups may create some steric hindrance, potentially affecting how well the molecule interacts with water.

As a general observation, compounds with intramolecular interactions or sterically hindered groups may exhibit moderate solubility. However, the dioxolane ring provides some stability while also allowing for interactions with polar environments. This leads to the conclusion that:

  • It is primarily soluble in polar solvents, particularly alcohols and water.
  • It may show decreasing solubility in non-polar solvents due to lack of favorable interactions.

In summary, the solubility of (2,2-dimethyl-1,3-dioxolan-4-yl)methanol can be viewed as favorable in polar media while being less favorable in non-polar solvents, creating a complex profile that is influenced by its unique molecular architecture.

Interesting facts

Interesting Facts About (2,2-dimethyl-1,3-dioxolan-4-yl)methanol

(2,2-dimethyl-1,3-dioxolan-4-yl)methanol represents a fascinating class of organic compounds known for their unique structural features and potential applications in various fields. Here are a few intriguing insights into this compound:

  • Structural Innovation: The presence of both a dioxolane ring and a hydroxymethyl group allows this compound to exhibit unique reactivity and stability, making it a subject of interest in synthetic organic chemistry.
  • Diverse Applications: Compounds like (2,2-dimethyl-1,3-dioxolan-4-yl)methanol are explored for their potential roles as solvents and in polymer chemistry. They may serve as intermediates in the synthesis of larger, more complex molecules.
  • Environmental Impact: Many dioxolane derivatives are evaluated for their environmental friendliness and biodegradability, which is critical in the move towards sustainable chemical practices.
  • Research Focus: Continuous research is being conducted to understand the the properties and behaviors of dioxolane derivatives, which informs their application in pharmaceuticals and agrochemicals.
  • Challenges in Synthesis: The synthesis of such compounds can pose significant challenges due to the need for specific conditions and the stability of the rings involved, thus offering an exciting challenge for chemists.

In summary, (2,2-dimethyl-1,3-dioxolan-4-yl)methanol is more than just a chemical formula; it embodies the intersection of innovation, research, and application in modern chemistry. As noted by leading chemists, "Exploration of unique compounds unlocks new pathways for innovation."

Synonyms
Solketal
100-79-8
2,2-Dimethyl-1,3-dioxolane-4-methanol
(2,2-Dimethyl-1,3-dioxolan-4-yl)methanol
DL-1,2-Isopropylideneglycerol
Glycerolacetone
Isopropylidene glycerol
Glycerol dimethylketal
1,2-O-Isopropylideneglycerol
1,2-Isopropylideneglycerol
2,3-Isopropylideneglycerol
1,3-Dioxolane-4-methanol, 2,2-dimethyl-
Glycerol acetonide
Acetone monoglycerol ketal
2,2-Dimethyl-4-(hydroxymethyl)-1,3-dioxacyclopentane
Acetone glycerol
1,2-Isopropylideneglycerin
Glycerinisopropylidene ether
2,3-(Isopropylidenedioxy)propanol
2,3-O-Isopropylideneglycerol
2,2-Dimethyl-1,3-dioxolan-4-ylmethanol
2,2-Dimethyl-4-hydroxymethyldioxolane
1,2-O,O-Isopropylideneglycerin
2,2-Dimethyl-4-hydroxymethyl-1,3-dioxolane
Glycerol acetonide (VAN)
Glycerol, 1,2-O-isopropylidene
MFCD00063238
NSC 59720
2,2-Dimethyl-5-hydroxymethyl-1,3-dioxolane
4-Hydroxymethyl-2,2-dimethyl-1,3-dioxolane
alpha,beta-Isopropylideneglycerol
Glycerolacetonide
2,2-Dimethyl-4-oxymethyl-1,3-dioxolane
2,2-Dimethyl-1,3-dioxolan-4-yl methanol
EINECS 202-888-7
Acetone, cyclic (hydroxymethyl)ethylene acetal
(+/-)-2,2-Dimethyl-1,3-dioxolane-4-methanol
BRN 0104465
3XK098O8ZW
36543-79-0
AI3-03547
NSC-59720
.alpha.,.beta.-Isopropylideneglycerol
ACETONE GLYCERIN KETAL
GIE
DTXSID9021845
1,2-Isopropylidene-rac-glycerol
EC 202-888-7
5-19-02-00362 (Beilstein Handbook Reference)
ISOPROPYLIDENE GLYCEROL [MI]
2,2-Dimethyl-1,3-dioxolan-4-yl methanol [IUPAC]
R-(-)-Sollketal
(2,2-dimethyl-[1,3]dioxolan-4-yl)-methanol
(r,s)-2,2-dimethyl-1,3-dioxolane-4-methanol
(+/-)-2,2-Dimethyl-4-hydroxymethyl-1,3-dioxolane
D-Acetone glycerol
2,2-Dimethyl-1,3-dioxolan-4-yl methanol (IUPAC)
2,3-Isopropylidene-sn-glycerol
UNII-3XK098O8ZW
Racemic solketal
MFCD00063239
(RS)-Solketal
2,3-dioxacyclopentane
1,2Isopropylideneglycerin
1,2Isopropylideneglycerol
1,3-Dioxolane-4-methanol, 2,2-dimethyl-, (S)-
2,3Isopropylideneglycerol
1,2OIsopropylideneglycerol
1,O-Isopropylideneglycerin
1,2-isopropylidene glycerol
Glycerol,2-O-isopropylidene
SCHEMBL23556
1,2O,OIsopropylideneglycerin
2,3-dioxolan-4-yl methanol
DL-1,2-isoproylideneglycerol
Glycerol, 1,2Oisopropylidene
1,2-o-isopropylidene glycerol
alpha,betaIsopropylideneglycerol
4-Hydroxymethyl-2,3-dioxolane
DTXCID901845
SCHEMBL3991160
1.2-isopropylidene-rac-glycerol
CHEMBL3342436
2,3(Isopropylidenedioxy)propanol
2,2Dimethyl1,3dioxolane4methanol
2,2Dimethyl4hydroxymethyldioxolane
2,2Dimethyl4oxymethyl1,3dioxolane
dimethyl-1,3-dioxolane-4-methanol
BCP26373
NSC59720
2,2Dimethyl1,3dioxolan4yl methanol
(.+/-.)-Glycerol 1,2-acetonide
1,3Dioxolane4methanol, 2,2dimethyl
AC-364
BBL012719
STK803305
WLN: T5O COTJ B1 B1 D1Q
2,2Dimethyl5hydroxymethyl1,3dioxolane
4Hydroxymethyl2,2dimethyl1,3dioxolane
AKOS000120075
AKOS022060550
CS-W018546
MI03369
(-)-2,3-O-Isopropylidene-sn-glycerol
2,2-dimethyl-1,3-dioxolan-4-methanol
2,2-dimethyl-1,3-dioxolane4-methanol
Dimethyl-4-hydroxymethyl-1,3-dioxolane
2,3-(dimethylmethylenedioxy)-1-propanol
dl-.alpha.,.beta.-Isopropylideneglycerol
(.+/-.)-1,2-O-Isopropylideneglycerol
AS-46670
SY010573
SY017180
SY017621
(2,2-dimethyl-1,3-dioxolan-4yl)methanol
2,2-dimethyl-[1,3]dioxolane-4-methanol
DB-011643
DL-1,2-Isopropylideneglycerol, >=97.0%
(2,2-dimethyl[1,3]dioxolan-4-yl)methanol
2,2-Dimethyl-4-hydroxymethyl-1,3-dioxolan
4-hydroxymethyl-2,2-dimethyl-1,3-dioxolan
D0710
NS00001386
(2,2-dimethyl-[1,3]dioxolan-4-yl)methanol
EN300-20586
(-)-2,2-Dimethyl-1,3-dioxolane-4-methanol
(2,2-dimethyl-[1,3]dioxolan-4-yl) -methanol
(4RS)-2,2-dimethyl 1.3-dioxolane-4-methanol
(4RS)-2,2-Dimethyl-1,3-dioxolane-4-methanol
2,2Dimethyl4(hydroxymethyl)1,3dioxacyclopentane
(rac)-2,2-dimethyl-[1,3]-dioxolane-4-methanol
2,2-dimethyl-1,3-dioxolane4-methanol (solketal)
2,2dimethyl-1,3-dioxolane-4-methanol (solketal)
rac-(2,2-dimethyl-[1,3]dioxolan-4-yl)-methanol
rac-(2,2-dimethyl-[1,3]dioxolan-4-yl)methanol
(R)-(?)-2,2-Dimethyl-1,3-dioxolane-4-methanol
(S)-(+)-2,2-Dimethyl-1,3-dioxaolane-4-methanol
2,2-dimethyl-1,3-dioxolane-4-methanol (solketal)
Q2968854
[(4R/S)-2,2-Dimethyl-1,3-dioxolan-4-yl]methanol
F0001-0027
Z104479028
202-888-7
Solketal;2,2-Dimethyl-4-(hydroxymethyl)-1,3-dioxacyclopentane;2,2-Dimethyl-1,3-dioxolane-4-methanol;2,2-Dimethyl-4-hydroxymethyl-1,3 -dioxolane