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2,2,4,4-Tetrakis(trifluoromethyl)-1,3-dithietane

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Identification
Molecular formula
C6F12S2
CAS number
813-60-1
IUPAC name
2,2,4,4-tetrakis(trifluoromethyl)-1,3-dithietane
State
State

At room temperature, 2,2,4,4-tetrakis(trifluoromethyl)-1,3-dithietane exists in a liquid state. It has a low boiling point and is highly volatile, necessitating careful storage conditions to prevent vapor loss and ensure safety.

Melting point (Celsius)
2.00
Melting point (Kelvin)
275.15
Boiling point (Celsius)
38.00
Boiling point (Kelvin)
311.15
General information
Molecular weight
344.08g/mol
Molar mass
344.0840g/mol
Density
2.1000g/cm3
Appearence

2,2,4,4-Tetrakis(trifluoromethyl)-1,3-dithietane appears as a colorless liquid. It does not have a distinctive odor and is often handled in sealed systems to prevent exposure to moisture and air.

Comment on solubility

Solubility of 2,2,4,4-tetrakis(trifluoromethyl)-1,3-dithietane

The solubility of 2,2,4,4-tetrakis(trifluoromethyl)-1,3-dithietane is an intriguing aspect to consider due to the presence of numerous trifluoromethyl groups. These groups significantly influence the compound's physical properties and behavior in different solvents.

  • Polarity: The trifluoromethyl groups are highly electronegative and contribute to the overall polarity of the molecule, making it less soluble in polar solvents.
  • Solvent Interaction: This compound is expected to exhibit limited solubility in water due to hydrophobic characteristics, while potentially being more soluble in organic solvents such as dichloromethane or acetone.
  • Temperature Effect: Generally, as temperature increases, solubility can also increase; however, for compounds like this, behavior can vary significantly.

As a conclusion, one could state that the solubility of 2,2,4,4-tetrakis(trifluoromethyl)-1,3-dithietane is largely influenced by its structure and the nature of the solvent, highlighting the need for detailed solubility studies to understand its full behavior in various environments.

Interesting facts

Interesting Facts about 2,2,4,4-Tetrakis(trifluoromethyl)-1,3-dithietane

The compound 2,2,4,4-tetrakis(trifluoromethyl)-1,3-dithietane is a fascinating example of coordination and reactivity in organofluorine chemistry. Here are some engaging facts that showcase its significance and unique properties:

  • Architectural Complexity: This compound is distinguished by its highly symmetrical structure, featuring four trifluoromethyl groups attached to the dithietane framework, which enhances its electronic properties.
  • Substituent Impact: The presence of trifluoromethyl groups significantly influences the chemical reactivity, making the compound an excellent agent in nucleophilic substitution reactions.
  • Applications: Due to its unique structure, this compound is of interest in the development of materials with specialized functionalities, such as:
    • Fluorinated solvents
    • Pharmaceutical intermediates
    • Advanced polymer synthesis
  • Electrochemical Properties: The heavy fluorination increases the electron-withdrawing capability, making it a strong candidate for various electrochemical applications.
  • Aromatic Interactions: The fluorine atoms introduce supramolecular interactions, which can be leveraged to create novel hydrogen-bonding environments.

The study of 2,2,4,4-tetrakis(trifluoromethyl)-1,3-dithietane not only provides insights into the behavior of fluorinated compounds but also opens avenues for innovation in chemical synthesis and materials science. As stated by renowned chemist John M. Brown, "Understanding the subtleties of such compounds allows us to push the boundaries of what is chemically possible."


Synonyms
791-50-4
2,2,4,4-tetrakis(trifluoromethyl)-1,3-dithietane
2,2,4,4-Tetra(trifluoromethyl)-1,3-dithiacyclobutane
Hexafluorothioacetone dimer
1,3-Dithietane, 2,2,4,4-tetrakis(trifluoromethyl)-
QCC36T3ZR9
BRN 1257024
AI3-61955
NSC-359467
1,3-DITHIACYCLOBUTANE, 2,2,4,4-TETRA(TRIFLUOROMETHYL)-
tetrakis(trifluoromethyl)-1,3-dithietane
DTXSID00229537
5-19-01-00089 (Beilstein Handbook Reference)
NSC 359467
DTXCID50152028
895-304-0
NSC359467
UNII-QCC36T3ZR9
SCHEMBL4420545
AKOS037621787
CS-0236425
EN300-1709109
Hexafluorothioacetone Dimer; 1,1,1,3,3,3-Hexafluoro-2-propanethione Dimer;