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Trithiane

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Identification
Molecular formula
C9H18S3
CAS number
1692-97-9
IUPAC name
2,2,4,4,6,6-hexamethyl-1,3,5-trithiane
State
State

At room temperature, this compound is typically a solid.

Melting point (Celsius)
93.50
Melting point (Kelvin)
366.65
Boiling point (Celsius)
302.40
Boiling point (Kelvin)
575.55
General information
Molecular weight
192.41g/mol
Molar mass
192.4100g/mol
Density
1.0544g/cm3
Appearence

2,2,4,4,6,6-Hexamethyl-1,3,5-trithiane appears as colorless crystals or a white crystalline powder. It is often noted for its distinctive thione odor.

Comment on solubility

Solubility of 2,2,4,4,6,6-Hexamethyl-1,3,5-trithiane

The solubility of 2,2,4,4,6,6-hexamethyl-1,3,5-trithiane is generally characterized by its organic nature. This compound, being a thiane, exists in a unique chemical environment that influences its interactions with solvents. Its solubility can be assessed on multiple fronts:

  • Polar Solvents: 2,2,4,4,6,6-hexamethyl-1,3,5-trithiane exhibits low solubility in polar solvents such as water. The high degree of steric hindrance due to the bulky methyl groups reduces its interaction with polar molecules.
  • Non-Polar Solvents: Conversely, it is more likely to dissolve in non-polar solvents. Organic solvents like hexane or dichloromethane can facilitate dissolution owing to their similar non-polar characteristics.
  • Practical Implications: This solubility behavior makes the substance particularly useful in various chemical reactions where non-polar environments are preferred.

In summary, the solubility of 2,2,4,4,6,6-hexamethyl-1,3,5-trithiane is markedly influenced by its chemical structure and the surrounding solvent. As a rule of thumb, the governing principle of "like dissolves like" applies here, where non-polar solvents yield better solubility compared to their polar counterparts. Understanding this behavior is crucial for chemists working with this compound in laboratory settings.

Interesting facts

Exploring 2,2,4,4,6,6-Hexamethyl-1,3,5-trithiane

2,2,4,4,6,6-Hexamethyl-1,3,5-trithiane is a fascinating compound that belongs to the class of organosulfur compounds. Known for its unique structural characteristics, this compound serves as an interesting point of study in both chemical synthesis and applications. Here are some captivating facts about this trithiane:

  • Structure: This compound features a trithiane ring, which is a six-membered ring that contains three sulfur atoms and three carbon atoms. The presence of six methyl groups on the carbon atoms leads to increased steric hindrance, making it a subject of interest in understanding bonding and steric effects.
  • Reactivity: The reactivity of trithiane compounds can be essential for applications in synthetic organic chemistry. The sulfur atoms can act as nucleophiles in various reactions, facilitating the formation of complex organic molecules.
  • Applications: This compound has potential applications in the field of materials science, particularly in the development of polymers and other materials where sulfur-containing compounds enhance durability and performance.
  • Recognition: Compounds like 2,2,4,4,6,6-hexamethyl-1,3,5-trithiane are often used in the study of odoriferous substances, where sulfur compounds play a critical role in determining scents and flavors. The chemistry of thiols and thioethers is vital in fields ranging from food science to perfumery.
  • Environmental Impact: Investigating compounds like this trithiane also contributes to our understanding of sulfur's role in the environment, particularly its influence on air quality and pollutant formation.

As you delve into the chemistry of 2,2,4,4,6,6-hexamethyl-1,3,5-trithiane, you'll uncover layers of complexity that intersect with various scientific disciplines. Whether you are engaging in synthetic development or exploring the environmental ramifications, this compound stands as a testament to the intricate world of chemical compounds.

Synonyms
2,2,4,4,6,6-Hexamethyl-1,3,5-trithiane
Trithioacetone
2,2,4,4,6,6-Hexamethyl-S-trithiane
Hexamethyl-1,3,5-trithiane
Hexamethyl-S-trithiane
1,3,5-Trithiane, 2,2,4,4,6,6-hexamethyl-
S-Trithiane, hexamethyl-
tropical trithiane
FEMA No. 3475
s-TRITHIANE, 2,2,4,4,6,6-HEXAMETHYL-
BRN 0106323
UNII-L0ME5B2ZWY
L0ME5B2ZWY
EINECS 212-582-5
DTXSID2047723
TRITHIOACETONE [FHFI]
DTXCID1027712
nbnwhqawkfyfki-uhfffaoysa-n
828-26-2
MFCD00066341
Trithioaceton
C9H18S3
Trithioacetone, >=99%, FG
SCHEMBL2521113
CHEMBL3187896
FEMA 3475
CHEBI:174132
Tox21_302581
AC7778
AKOS015897635
CS-W020945
NCGC00256688-01
BS-18168
CAS-828-26-2
SY033151
H1278
NS00042477
EN300-7869230
2,2,4,4,6,6-Hexamethyl-1,3,5-trithiane #
Q11321962
2,2,4,4,6,6-Hexamethyl-S-trithiane (trithioacetone)