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2,3,3,4,4,5-Hexamethylhexane-2-thiol

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Identification
Molecular formula
C12H26S
CAS number
13963-58-1
IUPAC name
2,3,3,4,4,5-hexamethylhexane-2-thiol
State
State

At room temperature, 2,3,3,4,4,5-Hexamethylhexane-2-thiol is a liquid. It is typically stored in closed containers to prevent the release of its potent odor.

Melting point (Celsius)
-8.00
Melting point (Kelvin)
265.15
Boiling point (Celsius)
196.00
Boiling point (Kelvin)
469.15
General information
Molecular weight
190.37g/mol
Molar mass
190.3690g/mol
Density
0.8265g/cm3
Appearence

2,3,3,4,4,5-Hexamethylhexane-2-thiol is a colorless liquid with a characteristic odor. Its appearance is typical of many organosulfur compounds, which often have distinct and strong smells.

Comment on solubility

Solubility of 2,3,3,4,4,5-hexamethylhexane-2-thiol

The solubility of 2,3,3,4,4,5-hexamethylhexane-2-thiol, a thiol compound, presents unique characteristics worth exploring. Generally speaking, thiols can exhibit varying degrees of solubility in different solvents based on their chemical structure and functional groups.

Factors Influencing Solubility:

  • Polarity: The presence of the thiol (-SH) group contributes to some polar character, but the long hydrocarbon chain makes the compound predominantly nonpolar.
  • Hydrophobic Interactions: The extensive methyl groups enhance hydrophobic interactions, thus favoring solubility in nonpolar solvents.
  • Temperature: Like many organic compounds, solubility may increase with temperature, affecting how well it can dissolve in various environments.

Given these factors, 2,3,3,4,4,5-hexamethylhexane-2-thiol is likely to be soluble in organic solvents such as:

  • Hexane
  • Chloroform
  • Ether

However, it is expected to have limited solubility in polar solvents like water. As a general observation, "the greater the number of carbon atoms in a hydrocarbon chain, the lower the solubility in water." Thus, it is essential to consider both the hydrophobic and polar nature when predicting the solubility of thiol compounds.

Interesting facts

Interesting Facts about 2,3,3,4,4,5-Hexamethylhexane-2-thiol

2,3,3,4,4,5-Hexamethylhexane-2-thiol is not your everyday compound; it possesses unique characteristics and applications that make it noteworthy in the realm of chemistry. Here are some fascinating insights about this intriguing thiol:

  • Structure and Composition: This compound belongs to the class of thiols, which are known for their sulfur-containing functional group. The 'hexamethyl' prefix indicates the presence of multiple methyl groups attached to a hexane chain, adding complexity to its structure.
  • Odor Characteristic: Like many thiols, 2,3,3,4,4,5-hexamethylhexane-2-thiol is recognized for its strong and often unpleasant odor, reminiscent of rotten eggs. This property is largely attributed to the sulfur atom in its structure.
  • Applications in Industry: Thiols have important roles in various industries. They are often used in the synthesis of natural products, as well as in flavor and fragrance chemistry due to their intense aroma profiles. Chemists may employ this compound in research to create aromatic compounds.
  • Biological Significance: Thiols play crucial roles in biological systems, especially as antioxidants. They protect cellular components against oxidative stress and contribute to various biochemical pathways.
  • Environmental Impact: While 2,3,3,4,4,5-hexamethylhexane-2-thiol itself is not widely reported in environmental studies, thiols in general can interact with certain classes of pollutants, potentially influencing their behavior in the environment.

Overall, this compound exemplifies the diverse and sometimes unexpected roles that sulfur-containing compounds can have in both nature and industry. It serves as a reminder of the intricate relationships between structure, function, and application in the world of chemical science!

Synonyms
TERT-DODECANETHIOL
25103-58-6
tert-Dodecyl mercaptan
tert-Dodecylthiol
t-Dodecanethiol
2,3,3,4,4,5-hexamethylhexane-2-thiol
Sulfole 120
t-DDM
t-Dodecylmercaptan
G00MDQ58TB
DTXSID1025221
NCGC00091163-03
CCRIS 6030
terc.Dodecylmerkaptan [Czech]
EINECS 246-619-1
terc.Dodecylmerkaptan
BRN 1738382
TERT-DODECYL THIOL
T-DODECYL MERCAPTAN
UNII-G00MDQ58TB
DTXCID905221
SCHEMBL3332338
CHEMBL1325985
Tox21_400018
AKOS015900250
NCGC00091163-01
NCGC00091163-02
NCGC00091163-04
tert-Dodecylmercaptan (mixture of isomers)
CAS-25103-58-6
NS00019461
EC 246-619-1
3-01-00-01794 (Beilstein Handbook Reference)
Q2405872