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Explosive 'picramide' or ammonium picrate

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Identification
Molecular formula
C17H22N4O7
CAS number
943-39-5
IUPAC name
(2,6-dimethoxyphenyl)methyl-diethyl-ammonium;2,4,6-trinitrophenolate
State
State

This compound is typically a solid at room temperature, existing as a crystalline powder. Its solid-state nature is due to the aromatic structure and hydrogen bonding potential of the nitro groups which stabilize the lattice structure.

Melting point (Celsius)
81.50
Melting point (Kelvin)
354.65
Boiling point (Celsius)
200.50
Boiling point (Kelvin)
473.65
General information
Molecular weight
381.35g/mol
Molar mass
381.3450g/mol
Density
1.6500g/cm3
Appearence

The compound appears as yellow or orange crystalline solid due to the presence of the nitro groups which often impart a distinct color to aromatic compounds. It may exhibit shiny or reflective surfaces under bright light and is often crystalline in fine powder or small granule form.

Comment on solubility

Solubility of (2,6-dimethoxyphenyl)methyl-diethyl-ammonium; 2,4,6-trinitrophenolate

The solubility of the compound (2,6-dimethoxyphenyl)methyl-diethyl-ammonium; 2,4,6-trinitrophenolate can be intriguing due to its unique structural makeup. Here are some key points regarding its solubility:

  • Ammonium Salt Characteristics: The presence of the ammonium group generally indicates enhanced solubility in polar solvents, particularly water.
  • Steric Hindrance: The 2,6-dimethoxyphenyl ring may introduce steric hindrance, which can affect the overall interaction with the solvent.
  • Polar vs Non-Polar Solvents: It is likely soluble in polar solvents but may exhibit lower solubility in non-polar environments due to its ionic character.
  • pH Dependency: The solubility could also be pH-dependent, especially since it contains the reactive NO2 groups of 2,4,6-trinitrophenolate.

In summary, while the compound shows promising solubility traits owing to its ammonium structure, factors like steric hindrance and solvent polarity should be carefully considered. As highlighted, it is essential to experiment under various conditions to fully appreciate its solubility profile in different environments.

Interesting facts

Interesting Facts about (2,6-dimethoxyphenyl)methyl-diethyl-ammonium; 2,4,6-trinitrophenolate

The compound (2,6-dimethoxyphenyl)methyl-diethyl-ammonium; 2,4,6-trinitrophenolate offers a fascinating glimpse into the world of organic chemistry and its applications. Here are some key points to consider:

  • Dual Nature: This compound features both an ammonium moiety and a trinitrophenolate group, showcasing the intricate interplay between cationic and anionic components in organic synthesis.
  • Pharmaceutical Relevance: Compounds containing ammonium and phenolic segments are often investigated for their potential therapeutic properties. Their ability to interact with biological membranes makes them valuable in drug design.
  • Explosive Potential: The presence of the trinitrophenolate group, commonly associated with explosives, adds a unique dimension to the compound, raising important considerations regarding safety and handling during synthesis.
  • Synthesis Challenges: Preparing such complex compounds often requires sophisticated synthetic techniques, which can include multi-step reactions and careful purification processes.
  • Research Applications: Scientists are intrigued by how modifications to such compounds can alter their chemical behavior, leading to discoveries in fields ranging from environmental science to materials engineering.

On a broader scale, the study of such compounds enhances our understanding of molecular interactions and reactivity, serving as a critical component in the advancement of chemical science and its practical applications. As one researcher aptly noted, “In each compound, there lies a story waiting to be told through its synthesis and application.”

As we continue to explore the vast realm of organic compounds, entities like (2,6-dimethoxyphenyl)methyl-diethyl-ammonium; 2,4,6-trinitrophenolate remind us of the complexities and wonders that chemistry has to offer.

Synonyms
N,N-Diethyl-2,6-dimethoxybenzylamine picrate
BENZYLAMINE, N,N-DIETHYL-2,6-DIMETHOXY-, PICRATE
2-Diethylaminomethyl-1,3-dimethoxybenzenepicrate
Benzene, 2-diethylaminomethyl-1,3-dimethoxy-, picrate
29175-74-4
DTXSID70183435
RefChem:328799
DTXCID80105926