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Manool oxide

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Identification
Molecular formula
C15H22O2
CAS number
22966-85-4
IUPAC name
(3aS,6S,6aS,9aR,9bR)-6,9a-dimethyl-3-methylene-3a,4,5,6,6a,7,8,9b-octahydroazuleno[8,7-b]furan-2,9-dione
State
State
Manool oxide is in a liquid state at room temperature. Given its low melting point, it remains liquid in typical environmental conditions.
Melting point (Celsius)
-25.00
Melting point (Kelvin)
248.15
Boiling point (Celsius)
284.20
Boiling point (Kelvin)
557.35
General information
Molecular weight
224.33g/mol
Molar mass
224.3300g/mol
Density
1.0500g/cm3
Appearence

Manool oxide is a colorless oily liquid that is found in some essential oils. It typically exhibits transparency and a lack of color, resembling many other terpene compounds in terms of its liquid state.

Comment on solubility

Solubility of (3aS,6S,6aS,9aR,9bR)-6,9a-dimethyl-3-methylene-3a,4,5,6,6a,7,8,9b-octahydroazuleno[8,7-b]furan-2,9-dione

The solubility of (3aS,6S,6aS,9aR,9bR)-6,9a-dimethyl-3-methylene-3a,4,5,6,6a,7,8,9b-octahydroazuleno[8,7-b]furan-2,9-dione is a subject of interest due to its unique structural features. Understanding its solubility can provide insights into its potential applications and behavior in various solvents.

  • Nonpolar Solvents: This compound is likely to exhibit higher solubility in nonpolar solvents such as hexane or toluene due to its hydrophobic characteristics.
  • Polar Protic Solvents: In solvents like ethanol or methanol, the solubility may be limited because of conflicting polar traits due to the structure.
  • Polar Aprotic Solvents: Solubility in polar aprotic solvents may vary, depending on the specific interactions of the solvent with the compound's functional groups.

As a general trend, compounds with elaborate cyclic structures like this one often possess limited aqueous solubility. It’s important to note that:

  • Solubility is highly influenced by temperature and pressure.
  • Adding surfactants may improve solubility in certain scenarios.
  • Interactions with solvents’ molecular properties play a crucial role in determining overall solubility behavior.

In conclusion, the solubility of (3aS,6S,6aS,9aR,9bR)-6,9a-dimethyl-3-methylene-3a,4,5,6,6a,7,8,9b-octahydroazuleno[8,7-b]furan-2,9-dione can be complex, often requiring empirical testing to ascertain its precise behavior in different solvent environments.

Interesting facts

Interesting Facts about (3aS,6S,6aS,9aR,9bR)-6,9a-dimethyl-3-methylene-3a,4,5,6,6a,7,8,9b-octahydroazuleno[8,7-b]furan-2,9-dione

This complex organic compound is a part of a unique class of substances that is often explored for its intriguing structural characteristics and potential applications. Here are some fascinating insights about this compound:

  • Structural Complexity: The compound features a multi-ring system, including the azulene structure, which is notable for its non-alternant aromaticity. This gives rise to unique electronic properties.
  • Potential Activity: Compounds with similar structural motifs have been researched for their biological activities, including anti-inflammatory and antioxidant properties. This opens up exciting avenues in medicinal chemistry.
  • Natural Occurrence: Some related compounds are found in nature, particularly in various plant species, where they can play a role in defending against herbivores or pathogens.
  • Synthesis Challenges: The synthesis of such complex organic molecules often presents significant challenges, including multi-step reactions and the need for specific stereochemistry.
  • Applications in Material Science: Due to their unique properties, compounds like this one might find applications in the development of new materials, particularly in the fields of organic electronics or photonic devices.

"The beauty of organic chemistry lies in the complexity and diversity of the structures that can arise from simple building blocks."

As a chemist or student of chemistry, studying such compounds not only enhances your understanding of organic reactions and mechanisms but also allows you to appreciate the intricate relationships between structure and function in chemical compounds.

Synonyms
Damsin
Ambrosin, dihydro-
Dihydroambrosin
1216-42-8
(3aS,6S,6aS,9aR,9bR)-6,9a-dimethyl-3-methylidene-3a,4,5,6,6a,7,8,9b-octahydroazuleno[8,7-b]furan-2,9-dione
NSC 85249
Decahydro-6,9a-dimethyl-3-methylene-azuleneo(4,5-b)furan-2,9-dione
10alphaH-Ambros-11(13)-en-12-oic acid, 6beta-hydroxy-4-oxo-, gamma-lactone
10-alpha-H-AMBROS-11(13)-EN-12-OIC ACID, 6-beta-HYDROXY-4-OXO-, gamma-LACTONE
Azuleno(4,5-b)furan-2,9-dione, decahydro-6,9a-dimethyl-3-methylene-, (3aS-(3aalpha,6beta,6aalpha,9abeta,9balpha))-
(3aS,6S,6aS,9aR,9bR)-6,9a-dimethyl-3-methylidene-3a,4,5,6,6a,7,8,9b-octahydroazuleno(8,7-b)furan-2,9-dione
(3aS,6S,6aS,9aR,9bR)-6,9a-dimethyl-3-methylene-3a,4,5,6,6a,7,8,9b-octahydroazuleno(8,7-b)furan-2,9-dione
(3aS,6S,6aS,9aR,9bR)-6,9a-dimethyl-3-methylene-3a,4,5,6,6a,7,8,9b-octahydroazuleno[8,7-b]furan-2,9-dione
10alphaH-Ambros-11(13)-en-12-oic acid, 6beta-hydroxy-4-oxo-, gamma-lactone (8CI)
Azuleno(4,5-b)furan-2,9-dione, decahydro-6,9a-dimethyl-3-methylene-, (3aS-(3aalpha,6beta,6aalpha,9abeta,9balpha))-(9CI)
Damsine
CHEBI:4314
NSC85249
Azulene derivative
CHEMBL2286469
SCHEMBL18642932
DTXSID70923878
NSC-85249
NS00094027
C09386
Q27106332
10.alpha.H-Ambros-11(13)-en-12-oic acid, .gamma.-lactone
6,9a-Dimethyl-3-methylidenedecahydroazuleno[4,5-b]furan-2,9-dione
Azuleno[4,9-dione, decahydro-6,9a-dimethyl-3-methylene-, [3aS-(3a.alpha.,6.beta.,6a.alpha.,9a.beta.,9b.alpha.)]-