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Crownophane

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Identification
Molecular formula
C13H13NO4
CAS number
72310-06-8
IUPAC name
5,7,17,19-tetraoxa-13-azahexacyclo[11.11.0.02,10.04,8.015,23.016,20]tetracosa-2,4(8),9,15(23),16(20),21-hexaene
State
State

At room temperature, Crownophane is typically found as a white solid. Its solid state is due to the complex interactions between the symmetric macrocyclic structures present in its molecular build.

Melting point (Celsius)
149.00
Melting point (Kelvin)
422.15
Boiling point (Celsius)
325.00
Boiling point (Kelvin)
598.15
General information
Molecular weight
284.32g/mol
Molar mass
284.3180g/mol
Density
1.3887g/cm3
Appearence

Crownophane is notable for its colorless crystalline appearance. It typically forms as a crystalline solid that is sheenless, reflecting its chemical purity. Single crystals of this compound can be grown for study using crystallography methods including X-ray diffraction.

Comment on solubility

Solubility of 5,7,17,19-tetraoxa-13-azahexacyclo[11.11.0.02,10.04,8.015,23.016,20]tetracosa-2,4(8),9,15(23),16(20),21-hexaene

The solubility of 5,7,17,19-tetraoxa-13-azahexacyclo[11.11.0.02,10.04,8.015,23.016,20]tetracosa-2,4(8),9,15(23),16(20),21-hexaene is intriguing, primarily due to its complex structure. The solubility can depend significantly on several factors:

  • Polarity: The presence of multiple ether and nitrogen functionalities in its structure may enhance its solubility in polar solvents like water.
  • Hydrophobic regions: Certain portions of the molecule may also possess hydrophobic characteristics, which could lead to lower solubility in aqueous environments.
  • Temperature: Increased temperatures generally increase the solubility of most compounds, and this hexacyclic structure may exhibit similar behavior.
  • pH Levels: The solubility may vary with pH, especially if protonation states of the nitrogen atoms are involved.

Despite its complex architecture, predicting its solubility often requires experimental determination. In summary, solubility will likely be influenced by a delicate balance between its polar and non-polar characteristics, along with external conditions. As such, understanding the specific interactions of this compound with various solvents can provide insights into its practical applications.

Interesting facts

Interesting Facts about 5,7,17,19-tetraoxa-13-azahexacyclo[11.11.0.02,10.04,8.015,23.016,20]tetracosa-2,4(8),9,15(23),16(20),21-hexaene

The compound 5,7,17,19-tetraoxa-13-azahexacyclo[11.11.0.02,10.04,8.015,23.016,20]tetracosa-2,4(8),9,15(23),16(20),21-hexaene is a fascinating example of complex organic chemistry that illustrates the diversity of molecular structures in modern chemistry. Here are some captivating aspects about this compound:

  • Structural Complexity: This compound features an intricate system of multiple interconnected rings, showcasing the ability of chemistry to create elaborate frameworks from simple atoms.
  • Functional Groups: The presence of >odo 'oxa' and aza groups allows for interesting chemical reactivity, making this compound a template for exploring new chemical reactions.
  • Potential Applications: Due to its unique structure, this compound may be explored for use in materials science, pharmaceuticals, and organic electronics. The flexibility of its structure can lead to innovative applications.
  • Research Importance: Compounds like this one are often used in academic research to understand fundamental concepts of chemical bonding and molecular stability.

As a chemistry student, delving into the study of such complex compounds is both challenging and exhilarating. Understanding how to synthesize and manipulate these structures opens the door to the potential development of novel technologies and therapies. The quote, "Chemistry is the art of transformation," perfectly encapsulates the process of studying compounds like 5,7,17,19-tetraoxa-13-azahexacyclo[11.11.0.02,10.04,8.015,23.016,20]tetracosa-2,4(8),9,15(23),16(20),21-hexaene, inspiring a deeper appreciation for the importance of this field.

Synonyms
Tetrahydrocoptisine
4312-32-7
Stylopine
(-)-STYLOPINE
dl-Stylopine
(R,S)-Stylopine
7461-02-1
6,7,12b,13-Tetrahydro-4H-[1,3]dioxolo[4',5':7,8]isoquinolino[3,2-a][1,3]dioxolo[4,5-g]isoquinoline
(RS)-Stylopine
( inverted exclamation markA)-Stylopine
STYLOPINE, (-)-(RG)(CALL)
5,7,17,19-tetraoxa-13-azahexacyclo[11.11.0.02,10.04,8.015,23.016,20]tetracosa-2,4(8),9,15(23),16(20),21-hexaene
7461-02-1 (racemic)
NSC 110382
Coptisine, tetrahydro-
(.+-.)-Tetrahydrocoptisine
STYLOPINE, (+/-)-(P)
NSC-110382
(.+-.)-Stylopine
(.+/-.)-Stylopine
Stylopine, (.+-.)-
Stylopine (Trahydocoptisine)
Oprea1_614048
Stylopine, (.+/-.)-
SCHEMBL433598
(.+/-.)-Tetrahydrocoptisine
Stylopine (Tetrahydrocoptisine)
CHEMBL3343660
DTXSID50904180
UXYJCYXWJGAKQY-UHFFFAOYSA-N
HAA46102
HY-N0924
NSC110382
NSC404529
AKOS000277992
AKOS016843796
FT73995
NSC-404529
TETRAHYDROCOPTISINE;(-)-STYLOPINE
AS-77471
DB-050264
F17720
AC-542/20643024
Berbine,3:9,10-bis(methylenedioxy)-, (.+-.)-
Q28603617
Berbine, 2,3:9,10-bis(methylenedioxy)-, (.+/-.)-
4H-Bis[1,6-a:4',5'-g]quinolizine, 6,7,12b,13-tetrahydro-
4H-Bis[1,6-a:4',5'-g]quinolizine, 6,7,12b,13-tetrahydro-, (.+-.)-
4H-Bis[1,3]benzodioxolo[5,6-a:4',5'-g]quinolizine, 6,7,12b,13-tetrahydro-, (.+/-.)-
5,7,17,19-TETRAOXA-13-AZAHEXACYCLO[11.11.0.0(2),(1)?.0?,?.0(1)?,(2)(3).0(1)?,(2)?]TETRACOSA-2,4(8),9,15(23),16(20),21-HEXAENE
6,7,12b,13-Tetrahydro-4H-[1,3]dioxolo[4,5-g][1,3]dioxolo[4',5':7,8]isoquino[3,2-a]isoquinoline #