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Arsenic trioxide

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Identification
Molecular formula
As2O3
CAS number
1327-53-3
IUPAC name
arsenic(3+);oxygen(2-)
State
State

At room temperature, arsenic trioxide is a solid.

Melting point (Celsius)
313.00
Melting point (Kelvin)
586.15
Boiling point (Celsius)
465.00
Boiling point (Kelvin)
738.15
General information
Molecular weight
197.84g/mol
Molar mass
197.8410g/mol
Density
3.7400g/cm3
Appearence

Arsenic trioxide appears as an odorless white, crystalline powder. It is soluble in water and has a characteristic, gloss-like sheen when in solid form. When dissolved, it forms a clear solution.

Comment on solubility

Solubility of Arsenic(III) Oxide

Arsenic(III) oxide, represented by the chemical formula As3+O2-, exhibits intriguing solubility characteristics that are important for various applications and environmental considerations.

General Solubility Insights

In water, arsenic(III) oxide is known to have:

  • Low Solubility: It generally has low solubility in cold water but can dissolve more readily in hot water.
  • pH Dependence: Its solubility can increase in acidic solutions due to the formation of soluble arsenite ions.

Factors Affecting Solubility

The solubility of arsenic(III) oxide can be influenced by a number of factors:

  • Temperature: Higher temperatures often enhance solubility.
  • Presence of Complexing Agents: Organic ligands or other metal ions may improve solubility by forming complexes.
  • pH Level: The solubility is generally higher in more acidic environments.

It is essential to consider that the solubility characteristics of arsenic compounds can have significant implications for environmental science, toxicology, and industrial processes. Understanding these solubility properties is crucial to managing arsenic-contaminated sites and ensuring safe handling in various applications.

Interesting facts

Interesting Facts about Arsenic(III) Oxide

Arsenic(III) oxide, commonly referred to as arsenic trioxide, is a fascinating compound with a rich history and significant implications in both science and medicine. Here are some engaging facts about this intriguing substance:

  • Toxicology: Arsenic(III) oxide is notorious for its toxicity. It is classified as a carcinogenic agent, meaning that long-term exposure can increase the risk of various cancers. Understanding its toxicity profile is crucial for individuals working in environments where arsenic exposure may occur.
  • Historical References: This compound has been used throughout history—particularly in the fields of medicine and poison. In ancient times, it was employed in traditional medicine, often referred to as the "king of poisons."
  • Industrial Applications: Despite its toxicity, arsenic trioxide has industrial applications. It is particularly used in the production of glass and ceramics, providing certain properties that enhance product quality.
  • Pharmaceutical Developments: Interestingly, arsenic(III) oxide has found its way back into modern medicine, particularly in the treatment of acute promyelocytic leukemia (APL). It works as a chemotherapeutic agent to induce remission in patients.
  • Environmental Concerns: Arsenic compounds are significant environmental pollutants. They can contaminate soil and water sources, leading to widespread health issues in affected populations. Monitoring and remediation efforts are essential to mitigate these risks.
  • Unique Chemistry: The oxidation state of arsenic in this compound is +3, which significantly influences its chemical reactivity and behavior in various chemical environments.

In summary, arsenic(III) oxide is a compound that straddles a delicate balance between historical intrigue and modern scientific relevance. As researchers continue to explore its properties, both caution and insight are essential in harnessing its capabilities while safeguarding health and the environment.

Synonyms
arsenic trioxide
Arsenic oxide (As2O3)
arsenic(3+);oxygen(2-)
Arsenic(III) trioxide
Arsenic oxidearsenous trioxide
DTXSID0020103
Arsenious Acid Anhydride
RCRA waste no. P012
EINECS 215-481-4
UN1561
Arsenic trioxide [USAN:JAN]
DTXCID60820620
QTLQKAJBUDWPIB-UHFFFAOYSA-N
Tox21_112255
Arsenic trioxide [UN1561] [Poison]
CAS-1327-53-3
NS00076140
EC 215-481-4
SR-01000944371
SR-01000944371-1