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P-phenylenediamine sulfate

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Identification
Molecular formula
C6H8N2·H2SO4
CAS number
106-50-3
IUPAC name
benzene-1,4-diamine;sulfuric acid
State
State

At room temperature, P-phenylenediamine sulfate is in a solid state, appearing as white to off-white crystals. It can form different hydrates based on the environmental humidity and storage conditions.

Melting point (Celsius)
267.00
Melting point (Kelvin)
540.15
Boiling point (Celsius)
313.70
Boiling point (Kelvin)
586.85
General information
Molecular weight
254.30g/mol
Molar mass
254.2950g/mol
Density
1.4000g/cm3
Appearence

P-phenylenediamine sulfate typically appears as a white to off-white crystalline solid. The appearance may vary slightly depending on the degree of purity and the specific manufacturing process.

Comment on solubility

Solubility of Benzene-1,4-Diamine in Sulfuric Acid

Benzene-1,4-diamine, also known as p-phenylenediamine (PPD), exhibits interesting solubility characteristics when dissolved in sulfuric acid. This compound is generally soluble in various organic solvents; however, its behavior in sulfuric acid is particularly noteworthy. Here are some key points regarding its solubility in this strong acid:

  • Solubility: Benzene-1,4-diamine is soluble in concentrated sulfuric acid, forming a clear solution.
  • Complex Formation: The solvation process can lead to the formation of complexes between the diamine and the sulfuric acid, potentially altering its physical properties.
  • pH Influence: The solubility may be influenced by the pH of the solution; higher acidity typically enhances solubility.
  • Temperature Dependency: As with many compounds, increasing temperature may also affect the solubility of benzene-1,4-diamine in the acid.

Overall, the solubility of benzene-1,4-diamine in sulfuric acid demonstrates the compound's ability to integrate into a more complex chemical system, enhancing its utility in various chemical reactions and applications. Understanding these solubility properties is crucial for chemists working with this amine in industrial and laboratory settings.

Interesting facts

Interesting Facts about Benzene-1,4-Diamine and Sulfuric Acid

Benzene-1,4-diamine, also known as p-phenylenediamine (PPD), is a fascinating organic compound with a rich history and varied applications. Here are some intriguing aspects about this compound:

  • Key Structural Features: Benzene-1,4-diamine features two amine groups (-NH2) attached to a benzene ring, specifically at the 1 and 4 positions. This structural arrangement allows for unique chemical behavior and reactivity.
  • Industrial Uses: PPD is widely utilized in various industries:
    • In the production of dyes and pigments, especially for textiles and hair coloring.
    • As an intermediate in the synthesis of rubber chemicals and other materials.
    • In the manufacture of "permanent" hair dyes due to its ability to form stable bonds with keratin in hair.
  • Health Considerations: While PPD is valued for its applications, it is essential to handle it with care due to potential health risks. Some individuals may experience allergic reactions, particularly in hair dye formulations. Always follow safety guidelines when working with this compound.
  • Reaction with Sulfuric Acid: When combined with sulfuric acid, benzene-1,4-diamine can undergo sulfonation, which may alter its properties and reactivity. This reaction is significant in various organic syntheses and helps chemists create even more complex compounds.
  • Research Opportunities: Due to its intriguing chemical properties, PPD remains a subject of ongoing research in the fields of material science and pharmacology, where its properties and derivative compounds could lead to exciting applications.

As you explore the world of organic chemistry, the compounds like benzene-1,4-diamine remind us of the delicate balance between utility and safety, highlighting the importance of thoughtful chemical synthesis and application.

Synonyms
p-Phenylenediamine sulfate
16245-77-5
1,4-Benzenediamine, sulfate (1:1)
1,4-Benzenediamine, sulfate
UNII-S7IGM30961
COVASTYLE PPDS
COLOREX PPDS
HSDB 6256
1,4-BENZENEDIAMINE SULFATE
EINECS 240-357-1
DTXSID6066028
1,4-Benzenediamine sulfate (1:1)
1,4-BENZENEDIAMINE SULFATE [HSDB]
pPhenylenediamine sulfate
Benzene1,4diammonium sulphate
DTXCID7035224
P-PHENYLENEDIAMINE SULFATE [INCI]
240-357-1
1,4-Phenylenediamine Sulfate
benzene-1,4-diamine;sulfuric acid
MFCD00035510
159822-74-9
Benzene-1,4-diammonium sulphate
S7IGM30961
1,4-Diaminobenzene Sulfate
benzene-1,4-diamine; sulfuric acid
1,4-Diaminebenzene sulfate
SCHEMBL147074
UFPKLWVNKAMAPE-UHFFFAOYSA-N
JGA82274
AKOS015897360
BS-42135
DB-043524
DB-071285
NS00076369
P0175
ST50410338
E78821
A810373
Q27288781