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Phenylmercuric benzoate

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Identification
Molecular formula
C13H10HgO2
CAS number
66-74-2
IUPAC name
benzoic acid;phenylmercury
State
State

At room temperature, phenylmercuric benzoate is a solid. This compound, used historically in antiseptic and antimicrobial applications, maintains its integrity as a solid at room temperature, enabling its use in various formulations and applications.

Melting point (Celsius)
153.00
Melting point (Kelvin)
426.00
Boiling point (Celsius)
300.00
Boiling point (Kelvin)
573.00
General information
Molecular weight
414.82g/mol
Molar mass
414.8210g/mol
Density
2.3500g/cm3
Appearence

Phenylmercuric benzoate is typically found as a white or slightly yellow crystalline solid. It is known for its crystalline structure and may appear slightly different under various lighting conditions due to its crystalline nature.

Comment on solubility

Solubility of Benzoic Acid and Phenylmercury

Benzoic acid, with the chemical formula C7H6O2, is known for its moderate solubility in water. Typically, it dissolves to an extent of about 0.29 g per 100 mL at room temperature. The solubility can increase with temperature due to its non-ionic nature, which influences the interaction with water molecules. This compound is more soluble in organic solvents such as ethanol and ether, making it quite versatile for various applications.


On the other hand, phenylmercury, generally represented as C6H5HgX (where X may vary, such as chloride or acetate), exhibits significantly different solubility characteristics depending on its specific salt form.

  • Chloride salt: Generally low solubility in water.
  • Acetate salt: More soluble compared to other forms, allowing for better bioavailability.

Moreover, the presence of the mercury atom often contributes to a complex interaction with water, leading to variations in solubility depending on other substituents. As a result, the solubility of phenylmercury compounds is influenced by factors such as:

  • The nature of the anion present
  • Temperature and pH of the solution
  • Organic solvent interactions

In summary, the solubility profiles of benzoic acid and phenylmercury compounds highlight their unique chemical properties; with benzoic acid showing moderate solubility in water and organic solvents, while phenylmercury salts typically have a lower solubility in water but can vary widely based on specific forms.

Interesting facts

Interesting Facts about Benzoic Acid and Phenylmercury

Benzoic acid is an aromatic carboxylic acid, notable for its use in various applications ranging from food preservation to chemical synthesis. Here are some key highlights:

  • Natural Occurrence: Benzoic acid occurs naturally in many plants and is a component of various essential oils. It can be found in fruits such as berries, where it acts as a natural preservative.
  • Food Preservation: One of its most famous applications is as a food preservative. It helps prevent the growth of mold, yeast, and some bacteria, making it crucial for extending the shelf life of certain products.
  • pH Regulation: Due to its weak acidic properties, benzoic acid is utilized in buffering solutions, maintaining the desired pH levels in a variety of chemical reactions.

On the other hand, phenylmercury is a fascinating organomercury compound that has garnered attention in various fields, primarily due to its unique properties and controversial usage:

  • Historical Usage: Phenylmercury was once widely used as a fungicide and preservative in agriculture and lichens due to its antimicrobial properties.
  • Environmental Impact: With the increasing awareness of mercury's toxicity, the use of phenylmercury has diminished significantly, highlighting the importance of environmental and health considerations in chemical usage.
  • Research Tool: Despite its decline in usage, phenylmercury remains a subject of interest in research. Scientists study its interactions in biological systems, providing insights into mercury's effects on health and the environment.

Both compounds illustrate the dual-edged nature of chemistry; while they offer significant benefits, understanding their implications and using them responsibly is crucial in scientific practice.