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Bis(p-tolyl)mercury

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Identification
Molecular formula
Hg(C7H7)2
CAS number
103-68-4
IUPAC name
bis-p-tolylmercury
State
State

At room temperature, Bis(p-tolyl)mercury is a solid. Its organometallic nature and heavy metal content contribute to its stability as a solid under standard atmospheric conditions.

Melting point (Celsius)
193.00
Melting point (Kelvin)
466.00
Boiling point (Celsius)
335.00
Boiling point (Kelvin)
608.00
General information
Molecular weight
454.02g/mol
Molar mass
454.0160g/mol
Density
1.7300g/cm3
Appearence

Bis(p-tolyl)mercury typically appears as a cream-colored to slightly yellow crystalline solid. The compound often displays a lustrous sheen, characteristic of organometallic compounds containing heavy metal atoms like mercury.

Comment on solubility

Solubility of bis-p-tolylmercury

Bis-p-tolylmercury, with the chemical formula C13H12Hg, possesses unique characteristics when it comes to solubility. Understanding its solubility behavior is essential for its practical applications and handling.

  • General Solubility: Bis-p-tolylmercury is known to have limited solubility in water. This is attributed to its hydrophobic nature, due to the presence of bulky organic groups.
  • Solvent Interaction: It exhibits better solubility in organic solvents such as:
    • Chloroform
    • Toluene
    • Benzene
  • Temperature Influence: The solubility may increase with higher temperatures in organic solvents, facilitating its use in various chemical reactions.
  • Environmental Considerations: Its limited water solubility suggests that bis-p-tolylmercury may pose less risk of leaching into groundwater compared to more soluble compounds, but appropriate precautions should still be observed due to its mercury content.

In summary, bis-p-tolylmercury is sparingly soluble in water but shows improved solubility in non-polar organic solvents. This behavior is vital for chemists to consider when utilizing this compound in laboratory settings or industrial applications.

Interesting facts

Interesting Facts About Bis-p-tolylmercury

Bis-p-tolylmercury is a fascinating organomercury compound known for its unique chemical properties and applications. Here are some intriguing aspects of this compound:

  • Synthesis and Structure: This compound features a central mercury atom bonded to two p-tolyl groups (methyl-substituted phenyl groups). Its structure is a prime example of organomercury chemistry, which highlights the interplay between metallic mercury and organic groups.
  • Applications: Historically, bis-p-tolylmercury was utilized in the chemical industry, particularly as a catalyst and a reagent in organic synthesis. Its ability to form strong carbon-mercury bonds makes it significant in various reactions.
  • Toxicity Considerations: Like many mercury compounds, bis-p-tolylmercury is toxic, raising important safety and environmental concerns. It is crucial to handle this compound with care in laboratory settings, using appropriate safety gear and protocols.
  • Environmental Impact: Due to its mercury content, this compound poses ecological risks. Mercury compounds can bioaccumulate in the food chain, leading to detrimental effects on wildlife and human health.
  • Research Applications: In modern research, bis-p-tolylmercury serves as a subject of study for chemists interested in organometallic chemistry and toxicology. Investigating its properties can provide insights into mercury’s behavior in biological systems and environmental contexts.

As stated by many chemists, *"Understanding organomercury compounds like bis-p-tolylmercury is essential not just for chemistry but also for public health."* This statement emphasizes the dual nature of their utility and hazards.

Overall, bis-p-tolylmercury exemplifies the complexity of chemical research, bridging the gap between useful applications and precautions necessary to safeguard health and the environment.

Synonyms
DI-P-TOLYLMERCURY
Mercury, bis(4-methylphenyl)-
537-64-4
Bis(4-methylphenyl)mercury
p-Ditolymercury
Mercury, di-p-tolyl-
HT726CY8JQ
Bis(p-tolyl)mercury
EINECS 208-672-9
NSC 33535
NSC-33535
BIS(4-TOLYL)MERCURY
P-DITOLYLMERCURY [MI]
DTXSID6060216
BIS(P-METHYLPHENYL)MERCURY
p-Ditolylmercury
Mercury, di-p-tolyl-(8CI)
DTXCID9041493
208-672-9
Di-p-tolyl mercury
UNII-HT726CY8JQ
NSC33535
DI(P-TOLYL)MERCURY
Di-(4-methylphenyl)mercury
DB-052395
D0954
NS00079942
Q27280089