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Calcium oxalate

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Identification
Molecular formula
CaC2O4
CAS number
563-72-4
IUPAC name
calcium;oxalate
State
State

At room temperature, calcium oxalate is typically a solid. It is poorly soluble in water, which contributes to the formation of kidney stones when it is present in high concentrations in the urine.

Melting point (Celsius)
200.00
Melting point (Kelvin)
473.00
Boiling point (Celsius)
0.00
Boiling point (Kelvin)
0.00
General information
Molecular weight
128.10g/mol
Molar mass
128.0970g/mol
Density
2.2000g/cm3
Appearence

Calcium oxalate usually appears as a white, odorless powder or crystalline solid. It may also be found in various hydrated forms, which are also white or transparent crystals. Hydrated forms like calcium oxalate monohydrate can appear as needle-shaped or rosette-like crystals under a microscope.

Comment on solubility

Solubility of Calcium Oxalate

Calcium oxalate, with the chemical formula CaC2O4, exhibits unique solubility characteristics that are important in various biological and chemical contexts. Here are some key points regarding its solubility:

  • Low Solubility in Water: Calcium oxalate is known for its low solubility in water, which can be quantified to approximately 0.12 g/L at room temperature. This limited solubility can lead to precipitation under certain conditions.
  • Influence of pH: The solubility of calcium oxalate is notably affected by the pH of the solution. It tends to be less soluble in neutral or alkaline conditions, while its solubility increases in acidic environments.
  • Temperature Dependence: As with many solids, the solubility of calcium oxalate increases with temperature, although this increase is minimal compared to more soluble salts.
  • Organic Acids: The presence of organic acids, such as citric acid, can enhance the solubility of calcium oxalate by forming soluble complexes that further decrease its precipitation potential.
  • Biological Relevance: In biological systems, the low solubility of calcium oxalate plays a critical role, particularly in kidney stone formation, where supersaturation can lead to precipitation.

In summary, the solubility of calcium oxalate is characterized by its low water solubility, significant pH sensitivity, and the ability to form complexes with organic acids. Understanding these properties is crucial, not only in chemistry but also in various medical and environmental applications.

Interesting facts

Interesting Facts about Calcium Oxalate

Calcium oxalate is a fascinating compound with several noteworthy attributes that make it a subject of study in both chemistry and biology. Here are some key points:

1. Natural Occurrence

  • Calcium oxalate is commonly found in nature, particularly in plants. It is often present in the form of crystals within various plant tissues.
  • Plants such as spinach, rhubarb, and even certain species of orchids contain calcium oxalate, which plays a role in their physiology.

2. Biological Significance

  • In humans, calcium oxalate can form kidney stones—a condition affecting many individuals. Understanding its formation and prevention is crucial in medicinal chemistry.
  • While it may be harmful in large quantities, calcium oxalate is essential in plants as it helps in regulating calcium levels and deterring herbivores due to its sharp crystals.

3. Industrial Applications

  • Calcium oxalate is utilized in various industries, including the production of porcelain and ceramics. Its properties help enhance the strength and durability of final products.
  • In analytical chemistry, it serves as a reagent in the detection and quantification of calcium in different samples.

4. Unique Properties

  • The compound exists in several crystalline forms, such as whewellite and weddelite, each with its own unique arrangement of atoms.
  • Its varying solubility in different pH conditions makes it an interesting subject for studies in environmental chemistry and biogeochemical cycles.

Overall, calcium oxalate is a remarkable compound that bridges the gap between chemistry, biology, and industry, proving that even simple compounds can have complex roles in nature and human activities. As we continue to study and understand calcium oxalate, we unlock new avenues for innovation in health and materials science.

Synonyms
CALCIUM OXALATE
563-72-4
Ethanedioic acid, calcium salt (1:1)
CHEBI:60579
2612HC57YE
Oxalate, Calcium
RefChem:573536
Dihydrate, Calcium Oxalate
Trihydrate, Calcium Oxalate
Monohydrate, Calcium Oxalate
209-260-1
calcium;oxalate
Ethanedioic acid, calcium salt
DTXSID6027214
25454-23-3
Calciumoxalate
Calcium oxalat
UNII-2612HC57YE
EINECS 209-260-1
C2CaO4
Calcium oxalate (1:1)
SCHEMBL43709
CALCIUM OXALATE [MI]
DTXCID007214
CHEMBL3184709
QXDMQSPYEZFLGF-UHFFFAOYSA-L
Oxalic acid, calcium salt (1:1)
ETHANEDIOIC ACID CALCIUM SALT
Tox21_202746
AKOS015837658
AKOS015903449
NCGC00260294-01
CAS-563-72-4
FC168366
NS00080020
C17478
Q412399