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Mercury(II) chloride

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Identification
Molecular formula
HgCl2
CAS number
7487-94-7
IUPAC name
chloromercury
State
State

At room temperature, mercury(II) chloride is a solid. It is crystalline and can dissolve readily in water, where it forms a colorless solution. It is also soluble in other solvents such as ethanol, acetone, and ethyl acetate.

Melting point (Celsius)
276.00
Melting point (Kelvin)
549.15
Boiling point (Celsius)
302.00
Boiling point (Kelvin)
575.15
General information
Molecular weight
271.52g/mol
Molar mass
271.5200g/mol
Density
5.4430g/cm3
Appearence

Mercury(II) chloride appears as a white crystalline solid. It is odorless and highly soluble in water, forming clear solutions. Its crystalline form tends to be prismatic or needle-like.

Comment on solubility

Solubility of Chloromercury

The solubility of chloromercury, also known as mercuric chloride (HgCl2), presents several intriguing characteristics that are crucial to its behavior in different environments.

Key points regarding its solubility include:

  • In Water: Mercuric chloride is known to be soluble in water, with solubility levels around 70 g per liter at room temperature. This significant solubility enables its use in various chemical reactions and applications.
  • In Organic Solvents: Chloromercury exhibits varying degrees of solubility in organic solvents. It is soluble in alcohol and can be dissolved in acetone, which is beneficial for applications in organic synthesis.
  • Temperature Effects: Altering the temperature can impact solubility; typically, an increase in temperature enhances solubility in water.
  • Formation of Complexes: Chloromercury can form complexes with other compounds, influencing its solubility profile and making it even more versatile in different chemical contexts.

However, it's important to note:

  • The high toxicity of mercuric chloride necessitates careful handling and disposal considerations.
  • Due to its toxicity, solutions of chloromercury should be managed in compliance with relevant safety regulations and guidelines.

In summary, the solubility of chloromercury is not only influenced by its chemical properties but also by external conditions, making it a compound of interest in both laboratory and industrial settings. Its water solubility enables a range of applications, yet the associated risks highlight the need for responsible use.

Interesting facts

Interesting Facts about Chloromercury

Chloromercury, also known as mercury(I) chloride or calomel, is a fascinating compound with notable historical and present-day significance. Here are some interesting points about this remarkable compound:

  • Historical vs. Modern Use: Historically, chloromercury was widely used in medicine for its antiseptic properties. It was even prescribed as a remedy for syphilis before the advent of modern antibiotics.
  • Toxicity: Due to its mercury content, chloromercury is highly toxic, and its use has significantly declined in modern medicine. The awareness of the dangers associated with mercury exposure has led to rigorous safety regulations.
  • Analytical Chemistry: In laboratory settings, chloromercury compounds are often used in analytical procedures, such as determining the presence of chloride ions in biological samples.
  • Formation of Complexes: Chloromercury can form various organomercury compounds when reacted with organic substrates, leading to various applications in organic synthesis.
  • Unique Properties: Calomel is notable for its relatively high stability and can serve as a reference electrode in electrochemical applications due to its reproducible potential.
  • Environmental Presence: Due to its historical use and the persistence of mercury in the environment, understanding chloromercury's behavior in ecological contexts is vital for environmental chemistry.

In conclusion, while chloromercury is a compound steeped in a rich history of medicinal use and chemical applications, its toxicity serves as a reminder of the importance of safety and responsibility in the field of chemistry. As we delve deeper into the world of chemical compounds, studying the impacts and interactions of such substances remains a crucial aspect of scientific advancement.

Synonyms
Chloromercury
7546-30-7
Mercury (I) chloride
Precipite blanc
Mercury monochloride
Mercury protochloride
Mercurochloride [Dutch]
Cloruro mercuroso [Italian]
mercurychloride
Mercurochloride
Chlorquecksilber
Quecksilber chloruer [German]
C.I. 77764
Cloruro mercuroso
HgCl
Quecksilber(I)-chlorid [German]
Quecksilber chloruer
Hg2Cl2, Calomel
EINECS 231-430-9
Mercuous(I) chloride
AKOS024258140