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Diethyl 2-dimethoxyphosphinothioylsuccinate

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Identification
Molecular formula
C10H19O7PS
CAS number
88211-13-0
IUPAC name
diethyl 2-dimethoxyphosphorylsulfanylbutanedioate
State
State

At room temperature, diethyl 2-dimethoxyphosphorylsulfanylbutanedioate is typically in a liquid state. It may solidify upon cooling below its melting point.

Melting point (Celsius)
-20.00
Melting point (Kelvin)
253.15
Boiling point (Celsius)
320.00
Boiling point (Kelvin)
593.15
General information
Molecular weight
356.29g/mol
Molar mass
356.3400g/mol
Density
1.2800g/cm3
Appearence

This compound typically appears as a colorless to pale yellow liquid. The exact shade and clarity can vary depending on the specific sample and purity.

Comment on solubility

Solubility of diethyl 2-dimethoxyphosphorylsulfanylbutanedioate

Diethyl 2-dimethoxyphosphorylsulfanylbutanedioate (C10H19O7PS) showcases unique solubility characteristics that can influence its application in various fields. Understanding the solubility behavior of this compound is essential for effective utilization and handling. Here are some key aspects of its solubility:

  • Polarity Influence: The presence of hydrophilic groups such as the phosphonate and sulfonate moieties suggests that the compound may be polar and soluble in polar solvents like water.
  • Solvent Compatibility: It is likely soluble in organic solvents, including ethanol and acetone, which can enhance its utility in organic syntheses and reactions.
  • Temperature Effects: Solubility can be dependent on temperature, and it may increase with elevated temperatures, leading to better solvation in various mediums.
  • pH Sensitivity: The compound’s solubility may also respond to changes in pH, particularly due to its acidic functional groups, possibly making it more soluble in alkaline conditions.

In summary, the solubility of diethyl 2-dimethoxyphosphorylsulfanylbutanedioate is characterized by its interaction with different solvents and environmental conditions. Chemists and researchers should consider these attributes when working with this compound to ensure optimal outcomes in experiments and applications.

Interesting facts

Interesting Facts about Diethyl 2-Dimethoxyphosphorylsulfanylbutanedioate

Diethyl 2-dimethoxyphosphorylsulfanylbutanedioate is a fascinating organophosphorus compound that showcases the complexity and utility of phosphorus-containing molecules in organic chemistry. Here are some intriguing insights into this compound:

  • Structure and Functionality: This compound features a unique combination of functional groups, including phosphoryl and sulfanyl moieties, which play crucial roles in its reactivity and potential applications.
  • Reactivity: The presence of the phosphoryl group indicates potential for reactivity with nucleophiles, making it valuable in various synthetic pathways, including the construction of more complex organophosphorus compounds.
  • Biological Activity: Compounds with similar structures have been studied for their biological activity; some organophosphorus compounds exhibit *insecticidal*, *fungicidal*, or *herbicidal* properties, revealing a potential role in agriculture.
  • Applications in Organic Synthesis: Due to its diverse functional groups, it may serve as a versatile building block in the synthesis of pharmaceuticals or agrochemicals, highlighting the significance of organophosphate chemistry.
  • Chiral Centers: The compound contains chiral centers, adding a layer of complexity and the potential for enantioselective synthesis, which is significant in the development of chiral drugs.

In summary, Diethyl 2-dimethoxyphosphorylsulfanylbutanedioate represents a compelling intersection of reactivity, potential biological applications, and synthetic utility. Its intricate structure serves as a reminder of the importance of phosphorus in organic chemistry and the vast possibilities it holds for future research.

Synonyms
MALAOXON
1634-78-2
Oxycarbophos
Liromat
Malaoxone
Maloxon
Carbethoxy malaoxon
Malathion oxon
diethyl 2-dimethoxyphosphorylsulfanylbutanedioate
NCI-C08628
CCRIS 367
Malaoxan
HSDB 4047
O,O-Dimethyl S-1,2-bis(ethoxycarbonyl)ethyl phosphorothioate
DTXSID9020790
AI3-25634
Diethyl mercaptosuccinate S-ester with O,O-dimethyl phosphorothioate
2439JYF84Q
O,O-Dimethyl-S-(1,2-dicarbethoxy)ethyl phosphorothioate
S-(1,2-Diethoxycarbonyl)ethyl O,O-dimethyl phosphorothioate
Butanedioic acid, ((dimethoxyphosphinyl)thio)-, diethyl ester
DTXCID50790
Succinic acid, mercapto-, diethyl ester, S-ester with O,O-dimethyl phosphorothioate
O,O-Dimethyl S-(1,2-dicarbethoxy)ethyl phosphorothioate
Phosphorothioic acid, O,O-dimethyl ester, S-ester with 1,2-bis(ethoxycarbonyl)ethanethiol
CHEBI:6649
O,O-Dimethyl-S-1,2-bis(ethoxycarbonyl)ethyl phosphorothioate
Succinic acid, mercapto-, diethyl ester, S-ester with O,O-dimethylphosphorothioate
succinic acid, mercapto-, diethyl ester, dimethyl phosphate
MALATHION IMPURITY B [EP IMPURITY]
Butanedioic acid, [(dimethoxyphosphinyl)thio]-, diethyl ester
DIETHYL ((DIMETHOXYPHOSPHINO)THIO)BUTANEDIOATE
BUTANEDIOIC ACID, 2-((DIMETHOXYPHOSPHINYL)THIO)-, 1,4-DIETHYL ESTER
PHOSPHOROTHIOIC ACID, O,O-DIMETHYL ESTER, S-ESTER WITH DIETHYL MERCAPTOSUCCINATE
MALATHION IMPURITY B (EP IMPURITY)
2-((Dimethoxyphosphinyl)thio)butanedioic acid
2-[(Dimethoxyphosphinyl)thio]butanedioic acid
Diethyl 2-((dimethoxyphosphoryl)sulfanyl)succinate
Diethyl 2-[(dimethoxyphosphoryl)sulfanyl]succinate
DIETHYL [(DIMETHOXYPHOSPHINO)THIO]BUTANEDIOATE
MalathionOanalog
Butanedioic acid, 2-[(dimethoxyphosphinyl)thio]-, 1,4-diethyl ester
THIOATE
diethyl((dimethoxyphosphinyl)thio)butanedioate
NCI-CO8628
((dimethoxyphosphinyl)thio)butanedioic acid diethyl ester
phosphorothioic acid, O,O-dimethyl ester, S-ester with 1,2-bis(methoxy-carbonyl)ethanethiol
O,ODimethylS(1,2dicarbethoxy)ethyl phosphorothioate
dimethoxyphosphorylsulfanyl-succinic acid diethyl ester
O,ODimethyl S(1,2dicarbethoxy)ethyl phosphorothioate
O,ODimethylS1,2bis(ethoxycarbonyl)ethyl phosphorothioate
S(1,2Diethoxycarbonyl)ethyl O,Odimethyl phosphorothioate
O,ODimethyl S1,2bis(ethoxycarbonyl)ethyl phosphorothioate
Butanedioic acid, ((dimethoxyphosphinyl)thio)-, diethyl ester (9CI)
Diethyl mercaptosuccinate Sester with O,Odimethyl phosphorothioate
BUTANEDIOIC ACID, ((DIMETHOXYPHOSPHINYL)THIO)-, DIETHYL ESETER
MERCAPTOSUCCINIC ACID DIETHYL ESTER, S-ESTER WITH O,O-DIMETHYLPHOSPHOROTHIOATE
Phosphorothioic acid, O,Odimethyl ester, Sester with 1,2bis(ethoxycarbonyl)ethanethiol
Succinic acid, mercapto, diethyl ester, Sester with O,Odimethylphosphorothioate
SUCCINIC ACID, MERCAPTO-, DIETHYL ESTER, S-ESTER WITH O,O-DIMETHYLPHOSPHORO-
diethyl 2-[(dimethoxyphosphoryl)thio]succinate
diethyl 2-((dimethoxyphosphoryl)thio)succinate
CAS-1634-78-2
UNII-2439JYF84Q
Oxycarbophos, Liromat
DL-MALAOXON
SCHEMBL331031
CHEMBL1331476
CHEBI:141477
Tox21_202017
Tox21_301103
AKOS030254496
NCGC00091894-01
NCGC00091894-02
NCGC00091894-03
NCGC00091894-04
NCGC00255003-01
NCGC00259566-01
DA-55196
HY-119904
CS-0078320
Malaoxon, PESTANAL(R), analytical standard
NS00000705
C07498
Diethyl 2-[(dimethoxyphosphoryl)sulfanyl]succinate #
Q3270235
Malathion impurity B, European Pharmacopoeia (EP) Reference Standard