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Diethylmercury

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Identification
Molecular formula
C4H10Hg
CAS number
627-44-1
IUPAC name
diethylmercury
State
State

Diethylmercury is typically a liquid at room temperature.

Melting point (Celsius)
-21.00
Melting point (Kelvin)
252.15
Boiling point (Celsius)
160.00
Boiling point (Kelvin)
433.15
General information
Molecular weight
258.71g/mol
Molar mass
258.6990g/mol
Density
3.4580g/cm3
Appearence

Diethylmercury is a colorless liquid. It is highly toxic and is known for its ability to easily penetrate skin and latex gloves, making it very dangerous to handle. Extreme care is required when dealing with this compound, as it is a powerful neurotoxin.

Comment on solubility

Solubility of Diethylmercury

Diethylmercury (C4H10Hg) presents intriguing solubility characteristics due to its organomercury structure. This compound is known for its highly soluble properties in various organic solvents, demonstrating a strong propensity to dissolve in nonpolar solvents such as:

  • Hexane
  • Diethyl ether
  • Toluene

In contrast, diethylmercury has very limited solubility in polar solvents, particularly water, as the mercury center contributes significantly to its hydrophobic interactions. As a result, this compound exemplifies a significant divergence in solubility behaviors based on solvent polarity.

Furthermore, the solubility characteristics of diethylmercury can be summarized with the following points:

  1. High solubility in organic solvents.
  2. Low solubility in water.
  3. Potential for complexation with other chemical entities, which can affect solubility.

Due to its high toxicity and solubility in organic media, diethylmercury must be handled with extreme care, emphasizing the importance of understanding its solubility behavior in various chemical contexts.

Interesting facts

Interesting Facts About Diethylmercury

Diethylmercury, also known as ethylmercurithiosalicylic acid, is one of the most notable organomercury compounds, primarily due to its fascinating and yet hazardous properties. Here are some captivating insights into this compound:

1. Historical Significance

Diethylmercury is infamous for its use in the late 20th century, especially in the field of vaccine preservation. It was utilized in some vaccines for its antimicrobial properties, but later studies raised concerns regarding its toxicity, leading to its removal from most vaccine formulations.

2. Toxicological Profile

This compound is exceptionally toxic and can lead to severe neurotoxic effects. The following highlights its risk:

  • Highly toxic: Diethylmercury is absorbed through various routes, including inhalation and dermal contact.
  • Bioaccumulation: Once inside the body, it can substitute for other molecules, disrupting biological processes.
  • Symptoms of poisoning: Symptoms may include tremors, memory loss, and cognitive decline.

3. Chemical Behavior

As an organomercury compound, diethylmercury exhibits unique chemical characteristics that set it apart:

  • Reactivity: Diethylmercury can easily react with a range of organic and inorganic substances, making it an interesting compound for various chemical studies.
  • Stability: It is relatively stable except in the presence of strong acids or bases, where it can decompose.

4. Safety Considerations

Due to its extreme toxicity, handling diethylmercury requires rigorous safety protocols:

  • Personal protective equipment (PPE): Lab coats, gloves, and safety goggles are essential during any experimental procedures.
  • Containment measures: Work with this compound is typically conducted within a fume hood to prevent exposure.

5. Modern Research

Research surrounding diethylmercury is ongoing, as scientists aim to further understand its effects and potential applications in controlled settings, emphasizing the need for:

  • Evaluating safer alternatives: Especially in antimicrobial applications.
  • Investigating its mechanisms of action: To uncover insights into organomercury toxicity and the development of novel treatments.

In summary, diethylmercury remains a significant topic in both chemistry and toxicology due to its historical use, toxic effects, and ongoing research into safer practices and alternatives. As scientists, it is crucial to balance our curiosity about such compounds with a strong commitment to safety and ethical considerations.

Synonyms
DIETHYLMERCURY
Diethyl mercury
Mercury, diethyl-
EINECS 211-000-7
UNII-323TG9BTE8
BRN 3902990
323TG9BTE8
(C2H5)2Hg
DTXSID1060841
SPIUPAOJDZNUJH-UHFFFAOYSA-
4-04-00-04427 (Beilstein Handbook Reference)
DTXCID5043500
211-000-7
inchi=1/2c2h5.hg/c2*1-2;/h2*1h2,2h3;
spiupaojdznujh-uhfffaoysa-n
627-44-1
NS00075383
Q2503726