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Mercury(II) iodide

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Identification
Molecular formula
HgI2
CAS number
7774-29-0
IUPAC name
diiodomercury
State
State

At room temperature, mercury(II) iodide is a solid. It is usually found in its red crystalline form, which is stable at room temperature.

Melting point (Celsius)
259.00
Melting point (Kelvin)
532.00
Boiling point (Celsius)
350.00
Boiling point (Kelvin)
623.00
General information
Molecular weight
454.39g/mol
Molar mass
454.3940g/mol
Density
7.7000g/cm3
Appearence

Mercury(II) iodide appears as a bright red-orange, crystalline solid in its alpha form (below 126°C), which changes to a pale yellow color when it transitions to its beta form (above 126°C). The red form of mercury(II) iodide is often used as a pigment known as "mercury oxide red," while the yellow form is less common.

Comment on solubility

Solubility of Diiodomercury (HgI2)

Diiodomercury, also known by its systematic name mercury(II) iodide and represented by the chemical formula HgI2, exhibits a specific behavior regarding its solubility in various solvents.

Key Solubility Characteristics:

  • Solvent Type: Diiodomercury shows limited solubility in water. It is primarily known to be insoluble in this polar solvent.
  • In Organic Solvents: However, it is much more soluble in non-polar organic solvents such as chloroform and carbon disulfide, making it useful in certain organic synthesis applications.
  • Temperature Dependence: The solubility of diiodomercury can change with temperature variations; increased temperatures generally lead to increased solubility in organic solvents.

In conclusion, the solubility of diiodomercury is notably poor in aqueous solutions, contrasting with its better solubility in organic media. This dual nature makes it an intriguing compound for various chemical reactions and applications.

Interesting facts

Interesting Facts about Diiodomercury

Diiodomercury is a fascinating compound that captures the interest of chemists and students alike due to its unique properties and applications. Here are some intriguing aspects:

  • Historical Significance: Diiodomercury was historically used in medicine as a treatment for syphilis. Its significance in pharmacology marks an important chapter in the transition from traditional to modern medicinal practices.
  • Uses in Research: In contemporary chemistry, diiodomercury serves as a reagent in various synthesis reactions, especially in organic chemistry. This highlights its role in facilitating the exploration of new compounds and chemical processes.
  • Uncommon Composition: Composed of mercury and iodine, this compound exemplifies how elements from the same group in the periodic table—specifically Group 17, the halogens—can form stable compounds with heavy metals, leading to unique chemical properties.
  • Harmful Effects: While diiodomercury has interesting uses, it is important to note that both mercury and iodine can be toxic. The compound requires careful handling, illustrating the balance between utility and safety in chemistry.
  • Interesting Reactions: Diiodomercury can participate in deiodination reactions, wherein iodine is replaced by other groups, showcasing its reactivity and versatility in organic synthesis.

As you study diiodomercury, keep in mind the quote: "Chemistry is a science of transformation." This compound is a perfect example of how simple elements can come together to create something significantly different, illustrating the transformative nature of chemical science.

Synonyms
MERCURIC IODIDE
Red mercuric iodide
Hydrargyrum diodatum
Hydrargyrum bijodatum
HSDB 1211
EINECS 231-873-8
UNII-R03O05RB0P
R03O05RB0P
Sore Throat Left Side
alpha-mercuryiodide
dtxcid7022124
dtxsid9042124
Mercury(II) iodide
Mercury diiodide
diiodomercury
7774-29-0
HgI2
Mercuric iodide, red
alpha-Mercury(II) iodide
MERCURY (II) IODIDE
mercury(2+) diiodide
MFCD00011044
Mercury biniodide
Mercurius bijodatus
Hydrargyrum bijodatum [German]
iodure mercurique
iodeto de mercurio
ioduro di mercurio
yoduro de mercurio
mercury(2+) iodide
Mercuty (II) iodide
Mercury(II) iodide red
Mercury(II) iodate, 99%
Mercury(II) iodide, anhydrous
CHEBI:49659
AKOS015902935
DB04445
FM34860
Mercury(II) iodide, ACS reagent, >=99.0%
Mercury(II) iodide red, puriss., red, >=99%
Mercury(II) iodide, 99.999% trace metals basis
Mercury(II) iodide, p.a., ACS reagent, 99.0%
Q414632
Mercury(II) iodide red, ACS reagent, >=99.0% dry basis
Mercury(II) iodide red, purum p.a., red, >=99.0% (RT)
Mercury(II) iodide red, puriss. p.a., ACS reagent, red, >=99.0% (RT)
Mercury(II) iodide, anhydrous, beads, -10 mesh, 99.999% trace metals basis