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Diphenyliodonium nitrate

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Identification
Molecular formula
C12H10IN2O3
CAS number
2116-96-1
IUPAC name
diphenyliodonium;nitrate
State
State

At room temperature, diphenyliodonium nitrate is typically in a solid state.

Melting point (Celsius)
146.00
Melting point (Kelvin)
419.15
Boiling point (Celsius)
200.00
Boiling point (Kelvin)
473.15
General information
Molecular weight
343.11g/mol
Molar mass
343.1110g/mol
Density
1.6130g/cm3
Appearence

Diphenyliodonium nitrate typically appears as a colorless or pale yellow crystalline solid. It may have a mild aromatic odor, depending on its purity.

Comment on solubility

Solubility of Diphenyliodonium Nitrate

Diphenyliodonium nitrate, with the chemical formula C12H10INO3, exhibits interesting solubility characteristics that are worth noting. Its solubility can be influenced by several factors including temperature and the polarity of the solvent. Typically, diphenyliodonium salts are known to be soluble in organic solvents such as acetone, dimethyl sulfoxide (DMSO), and methanol. However, their solubility in water is generally limited.

Factors affecting solubility include:

  • Polarity of the solvent: Organic solvents often help dissolve non-polar or less polar compounds like diphenyliodonium nitrate.
  • Temperature: Higher temperatures can increase solubility, making it possible for more of the compound to dissolve.
  • Concentration: The amount of solvent used can significantly change how much diphenyliodonium nitrate dissolves.

In summary, while diphenyliodonium nitrate has limited solubility in water, it is readily soluble in various organic solvents, making it valuable for applications that require it in solution. Remember, the choice of solvent is key to maximizing the solubility of this compound!

Interesting facts

Interesting Facts About Diphenyliodonium Nitrate

Diphenyliodonium nitrate is a fascinating compound that has garnered interest in various fields, particularly in organic photochemistry and materials science. Here are some intriguing aspects of this compound:

  • Versatile Reactivity: Diphenyliodonium (DPI) is known for its ability to act as a powerful electrophile. This makes it valuable in many chemical reactions, particularly in the formation of new carbon-carbon bonds.
  • Photochemical Applications: The compound has unique photochemical properties that allow it to release superoxide radicals upon irradiation. This characteristic is particularly useful in the field of photopolymerization, where it can be employed as a photoinitiator.
  • Diagnostic Potential: DPI derivatives have potential applications in diagnostic techniques, enhancing the sensitivity of analytical methods, such as fluorometric assays.
  • Environmentally Friendly Chemistry: Research has suggested that diphenyliodonium compounds can facilitate environmentally sustainable processes, as they can reduce the need for toxic reagents commonly found in organic synthesis.
  • Stability and Safety: Despite its reactive nature, diphenyliodonium nitrate exhibits remarkable stability in solid form, making it safer to handle compared to other highly reactive electrophiles.

In summary, diphenyliodonium nitrate is not just an exciting compound for its reactivity, but also for its implications in various modern applications and its potential role in advancing sustainable chemistry. Its unique characteristics make it a subject of ongoing research and exploration in both academic and industrial laboratories.

Synonyms
Diphenyliodonium nitrate
Iodonium, diphenyl-, nitrate (1:1)
211-962-8
722-56-5
IODONIUM, DIPHENYL-, NITRATE
diphenyliodanium;nitrate
DPIN
NSC-90597
EINECS 211-962-8
NSC 90597
Antiflavog
MFCD00031704
Diphenyliodinium nitrate
RPZ6DQ47RQ
SCHEMBL52022
Diphenyliodonium nitrate, 98%
CHEMBL3391894
DTXSID00222528
CQZCVYWWRJDZBO-UHFFFAOYSA-N
AKOS015833428
FD11342
s11940
DS-11775
D2357
NS00080105