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Ethanethiol

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Identification
Molecular formula
C2H6S
CAS number
75-08-1
IUPAC name
ethanethiol
State
State

At room temperature, ethanethiol is a liquid. Its state allows it to be easily used in applications where a liquid form is advantageous, such as in the natural gas industry for odorization.

Melting point (Celsius)
-148.80
Melting point (Kelvin)
124.40
Boiling point (Celsius)
35.00
Boiling point (Kelvin)
308.15
General information
Molecular weight
62.13g/mol
Molar mass
62.1340g/mol
Density
0.8670g/cm3
Appearence

Ethanethiol is a clear liquid with a distinctly unpleasant odor reminiscent of rotten cabbage. It is often described as having a strong, pungent stench which makes it easily identifiable.

Comment on solubility

Solubility of Ethanethiol

Ethanethiol, also known as ethyl mercaptan, is a volatile compound with a distinctive odor. Its solubility characteristics are quite interesting:

  • Water Solubility: Ethanethiol is moderately soluble in water, exhibiting a solubility of approximately 6.7 g/100 mL at 20 °C.
  • Nonpolar Solvents: It is also soluble in various organic solvents such as ethanol, ethers, and chloroform.
  • Hydrogen Bonding: The presence of the thiol functional group (-SH) allows ethanethiol to engage in some hydrogen bonding, enhancing its solubility in polar solvents.
  • Density Considerations: Its relatively low molecular weight contributes to its volatility and influences its solubility behavior.

In summary, the solubility of ethanethiol in water and organic solvents can be attributed to its chemical structure and the ability to form hydrogen bonds, making it both an intriguing and versatile compound in the realm of chemistry.

Interesting facts

Interesting Facts about Ethanethiol

Ethanethiol, also known as ethyl mercaptan, is a fascinating organic compound with a variety of characteristics and applications worth exploring.

Key Characteristics

  • Structure: Ethanethiol consists of a two-carbon alkyl group attached to a thiol group, which is a sulfur-containing functional group. This unique structure gives ethanethiol its distinct properties.
  • Odor: One of the most notable features of ethanethiol is its strong, unpleasant smell, often described as similar to rotten cabbage. This odor is so potent that it is often used as an odorant for natural gas, serving as a safety measure to detect leaks.
  • Reactivity: As a thiol, ethanethiol exhibits a range of reactivity due to the presence of the sulfur atom. It can participate in nucleophilic substitutions and may form disulfides, making it a valuable compound in organic synthesis.

Applications

  • Odorant: Ethanethiol is most commonly utilized as a natural gas odorant to help prevent leaks and ensure safety in residential and commercial settings.
  • Organic Synthesis: In the field of organic chemistry, ethanethiol is often used as a building block for synthesizing a variety of compounds, including pharmaceuticals and agrochemicals.
  • Research: It is also used in laboratories for research purposes, particularly in studies involving sulfur compounds and their behavior.

Fun Fact

Due to its strong odor, even a small amount of ethanethiol can have a detectable scent. This property highlights the remarkable sensitivity of the human nose and is a prime example of how chemistry intersects with everyday life.

In summary, ethanethiol is more than just a compound with a strong smell; it showcases the intriguing chemistry of thiols and has practical applications that emphasize the importance of safety in our environments.

Synonyms
Ethanethiol
ETHYL MERCAPTAN
75-08-1
Mercaptoethane
Ethyl sulfhydrate
Thioethanol
Ethyl thioalcohol
Thioethyl alcohol
Ethyl hydrosulfide
Aethylmercaptan
Etilmercaptano
Aethanethiol
Etantiolo
1-Mercaptoethane
Ethaanthiol
Ethylmercaptaan
Ethylmerkaptan
ethyl-mercaptan
Mercaptan C2
LPG ethyl mercaptan 1010
NSC 93877
stench
HSDB 814
stench gas
1-ethanethiol
EINECS 200-837-3
UNII-M439R54A1D
AI3-26618
M439R54A1D
NSC-93877
DTXSID9026394
FEMA NO. 4258
CHEBI:46511
EC 200-837-3
ETHANETHIOL (MART.)
ETHANETHIOL [MART.]
Etantiolo [Italian]
Ethaanthiol [Dutch]
Aethanethiol [German]
ethanthiol
ethylmercaptan
Ethylmerkaptan [Czech]
Ethylmercaptaan [Dutch]
Aethylmercaptan [German]
Etilmercaptano [Italian]
UN2363
ethanethioi
ethanothiol
ethane thiol
1-Ethylthiol
EtSH
HSEt
Ethanethiol, 97%
MFCD00004887
Ethanethiol, >=97%
ETHANETHIOL [MI]
ETHANETHIOL [FHFI]
C2H5SH
WLN: SH2
ETHYL MERCAPTAN [HSDB]
DTXCID506394
Ethanethiol, analytical standard
NSC93877
AKOS000120313
UN 2363
MSK158171-1000M
DB-004032
E0036
NS00005388
EN300-20602
Ethanethiol Solution in Methanol, 1000ug/mL
InChI=1/C2H6S/c1-2-3/h3H,2H2,1H
Ethyl mercaptan [UN2363] [Flammable liquid]
Ethanethiol (ethyl mercaptan), analytical standard
Q407918
F0001-1889
QuadraPure(R) DET, 450-650 mum, extent of labeling: 1.0-2.0 mmol/g loading, macroporous
200-837-3
EUF