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Fluorotriphenylstannane

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Identification
Molecular formula
C18H15FSn
CAS number
379-52-2
IUPAC name
fluoro(triphenyl)stannane
State
State

At room temperature, fluorotriphenylstannane is in a solid state. It is often encountered in labs or in chemical markets as a fine crystalline solid that may require handling under an inert atmosphere to prevent hydrolysis.

Melting point (Celsius)
105.00
Melting point (Kelvin)
378.15
Boiling point (Celsius)
285.00
Boiling point (Kelvin)
558.15
General information
Molecular weight
403.00g/mol
Molar mass
403.0130g/mol
Density
1.6420g/cm3
Appearence

Fluorotriphenylstannane, also known as triphenyltin fluoride, typically appears as a white to off-white crystalline powder. It has a solid appearance and is handled in its solid form for most laboratory preparations and reactions.

Comment on solubility

Solubility of Fluoro(triphenyl)stannane

Fluoro(triphenyl)stannane, with the chemical formula F(C6H5)3Sn, presents intriguing properties when it comes to solubility. This compound, belonging to the organotin family, exhibits a few noteworthy characteristics:

  • Polarity: Due to the presence of the fluorine atom, fluoro(triphenyl)stannane displays some polar characteristics; however, the triphenyl groups contribute to its overall hydrophobic nature.
  • Solvent Compatibility: This compound is generally soluble in organic solvents such as:
    • Chloroform
    • Toluene
    • Ether
  • Low Aqueous Solubility: It is expected to be insoluble or very poorly soluble in water, which limits its use in aqueous environments.

As noted, the solubility of fluoro(triphenyl)stannane can be summarized as follows:

  1. Soluble in organic solvents
  2. Poorly soluble in water
  3. Effectively engages in non-polar environments

In essence, understanding the solubility profile of fluoro(triphenyl)stannane is essential for its application in chemical processes and synthesis. Knowing how it interacts with various solvents can aid in designing effective experimental methodologies.

Interesting facts

Interesting Facts about Fluoro(triphenyl)stannane

Fluoro(triphenyl)stannane is a fascinating organometallic compound that exhibits a range of interesting properties and applications in the field of chemistry. Below are some noteworthy aspects of this compound:

  • Organometallic Chemistry Pioneer: This compound belongs to a significant class of organometallic compounds where tin is bonded to organic groups, showcasing the versatility and diversity found in stannanes.
  • Fluorination Benefits: The presence of the fluoro group in its structure enhances chemical stability and reactivity, making it a valuable reagent for organic synthesis and material sciences.
  • Applications in Synthesis: Fluoro(triphenyl)stannane serves as a powerful intermediate in the synthesis of various complex organic molecules, including pharmaceuticals and agrochemicals, due to its ability to participate in nucleophilic substitutions and cross-coupling reactions.
  • Electrophilic Nature: The electrophilic character of the tin center allows for unique bonding interactions, making it an attractive candidate in designing new catalytic systems.
  • Insight into Carbon-Silicon Bond Formation: The compound has been extensively studied in the context of carbon-silicon (C-Si) bond formations, which are critical in developing new materials with improved properties.
  • Environmental Considerations: As researchers explore the environmental impact of organometallic compounds, fluoro(triphenyl)stannane represents an area of study focused on understanding its toxicity and potential ecological effects.

Overall, fluoro(triphenyl)stannane is more than just a chemical compound; it is a key player in advancing modern chemistry, demonstrating the intricate relationships between structure and reactivity in organometallic systems.

Synonyms
TRIPHENYLTIN FLUORIDE
379-52-2
Fentin fluoride
Fluorotriphenylstannane
Stannane, fluorotriphenyl-
Biomet 204
Tin, fluorotriphenyl-
fluoro(triphenyl)stannane
Caswell No. 896H
EINECS 206-833-8
UNII-1YP2L952MD
EPA Pesticide Chemical Code 083602
1YP2L952MD
DTXSID3042500
TIN TRIPHENYLFLUORIDE
DTXCID1022500
triphenyl tin fluoride
Triphenylzinnfluorid
Fluorotriphenylstannane 98%
Tox21_302241
MFCD00015356
NCGC00255906-01
CAS-379-52-2
DB-246437
NS00112448
Q27253227