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Corannulene

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Identification
Molecular formula
C20H10
CAS number
2873-69-2
IUPAC name
hexacyclo[12.12.0.03,12.04,9.016,25.019,24]hexacosa-1(14),2,4,6,8,10,12,15,17,19,21,23,25-tridecaene
State
State

At room temperature, corannulene is typically in a solid state, appearing as a crystalline or powdery material. It is stable under standard conditions.

Melting point (Celsius)
268.00
Melting point (Kelvin)
541.00
Boiling point (Celsius)
420.00
Boiling point (Kelvin)
693.00
General information
Molecular weight
496.62g/mol
Molar mass
496.6220g/mol
Density
1.4900g/cm3
Appearence

Corannulene typically appears as slightly yellow-tinged or white crystals or powder. It is known for its bowl-shaped aromatic structure, which resembles a fragment of the geodesic structure of a buckyball. This distinct architectural form contributes to its unique physical properties.

Comment on solubility

Solubility of Hexacyclo[12.12.0.03,12.04,9.016,25.019,24]hexacosa-1(14),2,4,6,8,10,12,15,17,19,21,23,25-tridecaene

Hexacyclo[12.12.0.03,12.04,9.016,25.019,24]hexacosa-1(14),2,4,6,8,10,12,15,17,19,21,23,25-tridecaene is a complex organic compound that exhibits intriguing solubility characteristics:

  • Solubility in Organic Solvents: This compound is expected to be more soluble in non-polar organic solvents such as hexane, toluene, or chloroform due to its extensive hydrocarbon structure.
  • Limited Solubility in Water: Given its large hydrophobic regions, water solubility is likely minimal, aligning with many large polycyclic compounds that tend to resist dissolution in polar solvents.
  • Temperature Influence: The solubility can vary with temperature; generally, an increase in temperature may enhance solubility in organic solvents.

It's important to note that chemists often look for solubility trends to predict behavior in reactions and formulations. As a rule of thumb:

  1. Compounds with larger hydrophobic surfaces typically exhibit decreased solubility in water.
  2. Polarity plays a critical role – non-polar compounds dissolve well in non-polar solvents.

Understanding these solubility properties is crucial for applications in materials science and organic chemistry, influencing everything from reaction mechanisms to the design of new materials.

Interesting facts

Interesting Facts about Hexacyclo[12.12.0.03,12.04,9.016,25.019,24]hexacosa-1(14),2,4,6,8,10,12,15,17,19,21,23,25-tridecaene

Hexacyclo[12.12.0.03,12.04,9.016,25.019,24]hexacosa-1(14),2,4,6,8,10,12,15,17,19,21,23,25-tridecaene is a fascinating compound with unique structural characteristics. This compound features an intricate polycyclic framework, making it a subject of significant interest in the field of organic chemistry. Here are some remarkable aspects:

  • Complex Structure: The compound consists of multiple interconnected cycles, showcasing the versatility and complexity that can be achieved in carbon-based compounds.
  • Potential Applications: Due to its unique structure, hexacyclo compounds may exhibit interesting electronic properties, potentially opening up avenues for applications in materials science, particularly in organic semiconductors.
  • Research Interest: Scientists are continuously exploring the synthesis and characterization of such compounds, leading to a better understanding of molecular interactions and the chemistry of larger polycyclic molecules.
  • Variation in Isomers: The existence of varied isomeric forms within this compound can allow for different chemical properties, making it an exciting area of study for chemists who investigate isomerism.
  • Historical Significance: Compounds like hexacyclo[12.12.0.03,12.04,9.016,25.019,24]hexacosa have historical ties to the development of organic synthesis, and they illustrate the progression of synthetic strategies over decades.

The study of hexacyclo[12.12.0.03,12.04,9.016,25.019,24]hexacosa-1(14),2,4,6,8,10,12,15,17,19,21,23,25-tridecaene not only showcases the aesthetic beauty of chemistry but also emphasizes the potential for new discoveries and innovations within the field. As chemists and students delve deeper into such compounds, who knows what breakthrough applications may emerge from this intricate architecture of carbon?

Synonyms
DIBENZO(A,L)NAPHTHACENE
226-86-8
DTXSID90177119
hexacyclo[12.12.0.03,12.04,9.016,25.019,24]hexacosa-1(14),2,4,6,8,10,12,15,17,19,21,23,25-tridecaene
Dibenzo[a,l]naphthacene
dibenzo[a,l]tetracene
DTXCID9099610
DB-220307