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Corannulene

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Identification
Molecular formula
C24H12
CAS number
191-55-7
IUPAC name
hexacyclo[14.6.2.02,11.05,10.013,23.020,24]tetracosa-1(23),2(11),3,5,7,9,12,14,16(24),17,19,21-dodecaene
State
State

At room temperature, Corannulene exists as a solid. Its unique structure results in a rigid, stable form that is distinct in its bowl-like shape.

Melting point (Celsius)
268.00
Melting point (Kelvin)
541.15
Boiling point (Celsius)
425.00
Boiling point (Kelvin)
698.15
General information
Molecular weight
300.36g/mol
Molar mass
300.3580g/mol
Density
1.4465g/cm3
Appearence

Corannulene is a polycyclic aromatic hydrocarbon that appears as colorless crystals. It is known for its bowl-shaped structure, which contributes to its unique chemical properties. The compound is not highly soluble in water, but it can dissolve in organic solvents.

Comment on solubility

Solubility of Hexacyclo[14.6.2.02,11.05,10.013,23.020,24]tetracosa-1(23),2(11),3,5,7,9,12,14,16(24),17,19,21-dodecaene

Hexacyclo[14.6.2.02,11.05,10.013,23.020,24]tetracosa-1(23),2(11),3,5,7,9,12,14,16(24),17,19,21-dodecaene is a complex organic compound characterized by its unique cyclic structure. When examining its solubility, several factors come into play.

Solubility Considerations:

  • Polarity: Due to its extensive ring structure, the compound exhibits a certain level of non-polar characteristics, which can hinder its solubility in polar solvents.
  • Solvent Interaction: It is likely to be more soluble in non-polar solvents such as hydrocarbons (e.g., hexane or toluene), while its solubility in polar solvents like water is expected to be quite low.
  • Cyclic Structure: The intricate structure presents multiple points of steric hindrance that may further limit solubility in various media.

In summary, the solubility of hexacyclo[14.6.2.02,11.05,10.013,23.020,24]tetracosa-1(23),2(11),3,5,7,9,12,14,16(24),17,19,21-dodecaene is likely minimal in polar solvents, while non-polar solvents may facilitate some degree of dissolution. This behavior illustrates an important principle in solubility: the adage “like dissolves like” holds true, emphasizing the relationship between solvent polarity and solute behavior.

Interesting facts

Interesting Facts about Hexacyclo[14.6.2.02,11.05,10.013,23.020,24]tetracosa-1(23),2(11),3,5,7,9,12,14,16(24),17,19,21-dodecaene

Hexacyclo[14.6.2.02,11.05,10.013,23.020,24]tetracosa-1(23),2(11),3,5,7,9,12,14,16(24),17,19,21-dodecaene is a fascinating chemical compound that showcases the ingenuity of organic chemistry. Below are some compelling highlights:

  • Structural Complexity: This compound is an example of a polycyclic structure, containing numerous interconnected rings. Such complexity contributes to a unique chemical behavior and reactivity.
  • Applications in Research: As a significant compound in supramolecular chemistry, it is studied for its potential applications in materials science and nanotechnology. Its intricate structure is ideal for creating advanced materials.
  • Source of Inspiration: The intricate molecular architecture has inspired organic chemists and material scientists to explore novel ways to manipulate molecular interactions, leading to innovative developments in pharmaceuticals and polymer science.
  • Connectivity in Chemistry: The connections within the cyclic structure allow for interesting electron delocalization, impacting the compound's stability and reactivity.
  • Historical Context: The study of such complex compounds has deep roots in the evolution of organic chemistry, marking milestones in synthetic methodologies and analytical techniques.

As a unique member of the polyene family, this compound demonstrates the beauty and complexity inherent in chemical structures, ultimately paving the way for discoveries that bridge science and technology.

Synonyms
benzo[pqr]picene
BENZO(PQR)PICENE
189-96-8
Naphtho(2,1-a)pyrene
naphtho[2,1-a]pyrene
Naphtho(3',4':3,4)pyrene
EINECS 205-879-6
DTXSID70172283
hexacyclo[14.6.2.02,11.05,10.013,23.020,24]tetracosa-1(23),2(11),3,5,7,9,12,14,16(24),17,19,21-dodecaene
Naphthol[2,1-a]pyrene
DTXCID6094774
NS00041483
205-879-6