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Mercuric Acetate

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Identification
Molecular formula
Hg(C2H3O2)2
CAS number
1600-27-7
IUPAC name
mercuric;diacetate
State
State

At room temperature, mercuric acetate is solid. It is often found in a crystalline state due to its acetate content.

Melting point (Celsius)
178.00
Melting point (Kelvin)
451.15
Boiling point (Celsius)
354.00
Boiling point (Kelvin)
627.15
General information
Molecular weight
318.68g/mol
Molar mass
318.6800g/mol
Density
3.2800g/cm3
Appearence

Mercuric acetate appears as a white crystalline solid or powder. It may also exhibit a faint odor of vinegar due to the acetic acid component of the compound. The solid form is efflorescent, meaning it can lose its water of hydration when exposed to air.

Comment on solubility

Solubility of Mercuric Diacetate

Mercuric diacetate, with the chemical formula Hg(C₂H₃O₂)₂, exhibits intriguing solubility characteristics. This compound is known for its moderate solubility in various solvents, which can be summarized as follows:

  • Solubility in Water: Mercuric diacetate is slightly soluble in water. This limited solubility is attributed to the polar nature of the acetate groups, which can interact to some extent with water molecules.
  • Solubility in Organic Solvents: It is more soluble in organic solvents such as ethanol and acetone. The nonpolar portion of the molecule tends to favor solvation by organic compounds.
  • pH Influence: The solubility can be affected by the pH of the solution. In more acidic conditions, solubility may increase due to the interaction of mercuric ions with hydronium ions.

It is essential to take into account the implications of solubility when handling mercuric diacetate, as its potential to dissolve in various media can lead to significant biological and environmental risks. As a quote from chemists often reminds us, "Solubility dictates availability." Therefore, understanding the solubility of mercuric diacetate is crucial for its safe and effective use in both laboratory and industrial settings.

Interesting facts

Interesting Facts about Mercuric Diacetate

Mercuric diacetate is a fascinating compound with a rich history in both industrial applications and academic research. Here are some key points that highlight its significance:

  • Chemical Composition: It is composed of mercury ions paired with two acetate groups, providing unique properties that have drawn interest from chemists and researchers alike.
  • Historical Significance: This compound has been utilized in chemistry since the 19th century, primarily for its capacity as a reagent in various organic syntheses, particularly in the formation of aryl halides and other complex molecules.
  • Reactivity: Mercuric diacetate is known for its ability to facilitate reactions such as acetylation processes and carbon-carbon bond formation, making it a valuable tool in synthetic organic chemistry.
  • Toxicity Awareness: Although it has useful applications, it is important to note that mercuric diacetate is highly toxic. This underscores the need for strict safety measures when handling it in the laboratory.
  • Environmental Concerns: Due to the toxicity of mercury compounds, proper disposal and limited release into the environment are crucial to prevent ecological damage.
  • Research Applications: In addition to synthetic uses, mercuric diacetate has been studied for its interactions in biochemical systems, offering insights into mercury’s behavior and effects on living organisms.

In summary, mercuric diacetate serves as both a powerful reagent in organic synthesis and a reminder of the importance of safety and environmental responsibility in chemical work. As noted by one researcher, "Understanding the intricacies of compounds like mercuric diacetate allows us to harness their potential while respecting their limitations."

Synonyms
Mercury(II) acetate
MERCURIC ACETATE
Mercury diacetate
Mercury di(acetate)
Mercury acetate
Caswell No. 543A
mercury (II) acetate
CCRIS 7488
HSDB 1244
UNII-R0G1MCT8Y5
EINECS 216-491-1
R0G1MCT8Y5
EPA Pesticide Chemical Code 052104
NSC 215199
DTXSID4042123
AI3-04458
mercury (2+) acetate
EINECS 209-766-2
MERCURIC ACETATE [MI]
MERCURIC ACETATE [HSDB]
DTXCID2022123
NSC-215199
592-63-2
Acetic acid, mercuridi
Mercury(II) acetic acid
(acetyloxy)mercurio acetate
MERCURIC(II) ACETATE
MERCURY(II) DIACETATE
DTXSID601015799
UN 1629
Anthracene, 1,4dihydro, compd. with mercury diacetate
209-766-2
(1:1)
acetic acid, mercury(2+) salt (2:1)
chebi:33211
1600-27-7
Diacetoxymercury
Mercuriacetate
Mercuric diacetate
Mercury(2+) acetate
Mercuryl acetate
Acetic acid, mercury salt
Acetic acid, mercury(2+) salt
Mercury acetate (Hg(CH3CO2)2)
Acetic acid, mercuridi-
Mercury acetate (Hg(O2C2H3)2)
UN1629
acetate mercurique
mercury(II)acetate
acetato de mercurio
acetato di mercurio
mercury(II)-acetate
mercury (II)-acetate
mercury(2+);diacetate
Hg(OAc)2
mercury (2+) diacetate
SCHEMBL18951
mercury(2+) bis(acetate ion)
Tox21_302000
AKOS015950690
FM44547
Mercury(II) acetate, A.C.S. reagent
Mercury acetate [UN1629] [Poison]
NCGC00255964-01
CAS-1600-27-7
NS00082996