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Methanethiol

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Identification
Molecular formula
CH4S
CAS number
74-93-1
IUPAC name
methanethiol
State
State

At room temperature, methanethiol exists as a gas. It is easily liquefied and normally handled as a liquefied compressed gas.

Melting point (Celsius)
-123.70
Melting point (Kelvin)
149.45
Boiling point (Celsius)
6.00
Boiling point (Kelvin)
279.15
General information
Molecular weight
48.11g/mol
Molar mass
48.1090g/mol
Density
0.8660g/cm3
Appearence

Methanethiol is a colorless gas that has a distinctive putrid smell, often compared to the smell of rotten cabbage. This characteristic odor is due to the presence of sulfur in its structure.

Comment on solubility

Solubility of Methanethiol (CH4S)

Methanethiol, also known as methyl mercaptan, exhibits interesting solubility characteristics that are important to consider:

  • Solubility in Water: Methanethiol is moderately soluble in water, with a solubility of approximately 2.4 g per 100 mL at 20 °C. This solubility is primarily due to its polar S-H bond, allowing it to interact with water molecules.
  • Solubility in Organic Solvents: It is highly soluble in organic solvents such as ethanol, ether, and chloroform. This makes it a versatile compound for various applications in organic synthesis.
  • Temperature Effects: The solubility of methanethiol in aqueous solutions can increase with rising temperature, making it more soluble at elevated temperatures. This temperature dependence is crucial in processes where methanethiol is utilized.

The unique properties of methanethiol's solubility not only impact its behavior in different environments but also play a significant role in its functionality as a reagent in chemical reactions.

Interesting facts

Interesting Facts about Methanethiol

Methanethiol, also known as methyl mercaptan, is a fascinating chemical compound with several intriguing attributes and applications that make it significant in both science and industry.

Chemical Properties and Structure

  • Structure: Methanethiol consists of a methyl group (-CH3) linked to a thiol group (-SH), making it the simplest thiol. Its straightforward molecular structure allows it to easily participate in various chemical reactions.
  • Flammability: Methanethiol is highly flammable, which introduces essential safety considerations when handling the compound in laboratory and industrial settings.
  • Odor: This compound is notorious for its strong, pungent smell, often compared to that of rotten cabbage or garlic, which is a reliable indicator of its presence even in minute quantities.

Biological Significance

  • Natural Occurrence: Methanethiol is produced naturally by several organisms, including bacteria and some human excretions, playing a role in the metabolism of sulfur-containing amino acids.
  • Signaling Molecule: Recent studies suggest that methanethiol may have a role in biological signaling, impacting various physiological processes.

Industrial Uses

  • Odorant Addition: Methanethiol is often added to natural gas as an odorant to impart a recognizable smell, serving as a crucial safety measure against gas leaks.
  • Chemical Intermediary: It is used in the production of other sulfur-containing compounds, making it valuable in the synthesis of pesticides and pharmaceuticals.

In conclusion, methanethiol's combination of unique properties and versatile applications makes it an essential compound in both chemical research and various industrial sectors. As you dive deeper into the world of chemistry, the intriguing behaviors and roles of compounds like methanethiol will truly enhance your understanding of the chemical landscape.

Synonyms
methanethiol
METHYL MERCAPTAN
Methylmercaptan
Mercaptomethane
74-93-1
Methyl sulfhydrate
Methanthiol
Thiomethanol
Thiomethyl alcohol
Metilmercaptano
Methvtiolo
Thiomethane
Methylmercaptaan
Mercaptan methylique
Methaanthiol
Methanethiole
Methanthiol [German]
methyl-mercaptan
CH3SH
FEMA No. 2716
Methyl thioalcohol
Methyl mercaptan (natural)
RCRA waste number U153
HSDB 813
methyl thiol
methyl-thiol
EINECS 200-822-1
MeSH
methylsulfanium
UN1064
UNII-2X8406WW9I
UN 1064
BRN 1696840
METHANETHIOL [MI]
METHYL MERCAPTAN [FHFI]
METHYL MERCAPTAN [HSDB]
DTXSID5026382
CHEBI:16007
EC 200-822-1
2X8406WW9I
4-01-00-01273 (Beilstein Handbook Reference)
METHANTHIOL (GERMAN)
Methaanthiol [Dutch]
Methvtiolo [Italian]
Methylmercaptaan [Dutch]
Metilmercaptano [Italian]
Metilmercaptano [Spanish]
Mercaptan methylique [French]
RCRA waste no. U153
methylsulfanyl
methane thiol
(methyl)sulfane
Methylthioalcohol
a methyl thioether
sulfonium methylide
Methanethiol, purum
METHANEETHIOL
Methanethiol (OSHA)
Methanethiol, 98.0%
Methanethiol, >=98.0%
DTXCID406382
Methyl mercaptan (ACGIH:OSHA)
DTXSID10168842
DTXSID60992376
NSC229573
AKOS009157032
METHYL MERCAPTAN (METHANETHIOL)
NSC-229573
Methyl mercaptan [UN1064] [Poison gas]
NS00020025
C00409
Q409309
17719-48-1
Z22