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Nitrite

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Identification
Molecular formula
NO2-
CAS number
14797-65-0
IUPAC name
nitrite
State
State

At room temperature, nitrite ions are typically found as part of ionic compounds, which are in solid state. Common nitrite salts like sodium nitrite (NaNO2) are stable solids at room temperature, often dissolved in water to form aqueous solutions.

Melting point (Celsius)
271.00
Melting point (Kelvin)
544.15
Boiling point (Celsius)
267.00
Boiling point (Kelvin)
540.15
General information
Molecular weight
46.01g/mol
Molar mass
46.0050g/mol
Density
1.9000g/cm3
Appearence

Nitrite compounds are generally crystalline in nature. They can appear as either white crystalline powders or colorless crystals, depending on the particular compound of nitrite in question, such as sodium nitrite or potassium nitrite.

Comment on solubility

Solubility of Nitrite (NO2-)

Nitrite, represented by the formula NO2-, is known for its interesting solubility characteristics. Generally, nitrite salts are readily soluble in water, making them widely used in various applications, including food preservation and as an additive in certain chemical processes. The factors affecting the solubility of nitrite can be categorized as follows:

  • Temperature: As temperature increases, the solubility of nitrite salts in water typically increases, following the general solubility trend.
  • pH Level: The solubility may vary with different pH levels. In more acidic conditions, certain forms of nitrite may become less soluble.
  • Presence of Ions: The solubility of nitrite can be influenced by the presence of other ions in solution, particularly those that might form precipitates with nitrite.

In summary, many nitrite compounds display high solubility in water, allowing them to easily partake in various chemical reactions and processes. This solubility aids in their utility across multiple fields, from agriculture to pharmaceuticals. It is essential to consider specific conditions, such as temperature and pH, that might affect their solubility characteristics.

Interesting facts

Interesting Facts about Nitrite (NO2-)

Nitrite is a fascinating anion that plays a significant role in various natural and industrial processes. As a chemical species, it is particularly notable for the following reasons:

  • Biological Importance: Nitrite can be a product of the microbial oxidation of ammonia. In many ecosystems, it serves as an intermediate in the nitrogen cycle, which is vital for soil health and fertility.
  • Food Preservation: In the food industry, nitrites are widely used as preservatives, particularly in curing meats. They help prevent bacterial growth, particularly from Clostridium botulinum, and also impart a distinctive flavor and color.
  • Environmental Science: Nitrite levels can indicate the degree of pollution in water bodies. High concentrations often signal the presence of excess nutrients, which can lead to problems such as eutrophication.
  • Health Perspectives: While nitrites have beneficial uses, their conversion into nitrosamines—particularly in the presence of amines—has raised health concerns. Scientists are investigating the implications of nitrite consumption and its potential associations with health risks.

Interesting Reactions

Nitrite is involved in a variety of interesting chemical reactions:

  • Reduction Reactions: Nitrite can be reduced to produce nitrogen oxide (NO) or even nitrogen gas (N2), depending on the conditions, which is significant in both ecological and industrial applications.
  • Color Change: It can react with various compounds to produce distinct colorimetric reactions, making it useful in analytical chemistry for detecting nitrites in environmental samples.

In summary, nitrite seems simple at a glance, yet it is a compound laden with complex roles and implications throughout various fields of science. As one explores its reactions and applications, the significance of nitrites becomes increasingly evident.

Synonyms
nitrite
Nitrite Ion
14797-65-0
Nitrite anion
Nitrous acid, ion(1-)
Nitrite(1-)
NO2-
Nitrit
Nitrite ion (NO2-)
Nitrogen dioxide ion(1-)
Nitrogen peroxide ion(1-)
dioxonitrate(III)
dioxonitrate(1-)
dioxidonitrate(1-)
UNII-J39976L608
DTXSID5024219
J39976L608
CHEBI:16301
NO2(-)
Water Supply QC Check Sample: Nitrite
Nitrites
Nitrite as N @ 1000 microg/mL in H2O
(NO2)(-)
[NO2](-)
Nitrite Standard: NO2- @ 1000 microg/mL in H2O
Nitrite Standard: NO2- @ 10000 microg/mL in H2O
Nitrite Standard
MFCD00144923
ONO-
CHEMBL1361
DTXCID704219
BDBM26989
DB12529
NCGC00090737-03
NCGC00090737-04
Nitrite as N @ 10000 microg/mL in H2O
AB01566909_01
Q213788