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Potassium Hydroxide

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Identification
Molecular formula
KOH
CAS number
1310-58-3
IUPAC name
potassium;hydroxide
State
State

At room temperature, potassium hydroxide is typically found as a solid, either in the form of pellets, flakes, or powders.

Melting point (Celsius)
360.00
Melting point (Kelvin)
633.00
Boiling point (Celsius)
1 327.00
Boiling point (Kelvin)
1 600.00
General information
Molecular weight
56.11g/mol
Molar mass
56.1060g/mol
Density
2.0440g/cm3
Appearence

Potassium hydroxide appears as a white crystalline solid. It can also exist as a colorless or white liquid in solution. When in its solid form, it is highly deliquescent, meaning it can absorb moisture from the air, and it dissolves readily in water with the release of significant heat.

Comment on solubility

Solubility of Potassium Hydroxide

Potassium hydroxide (KOH), known for its strong alkaline properties, exhibits notable solubility in water. Here are some key aspects of its solubility:

  • Highly Soluble: KOH is highly soluble in water, with a solubility of approximately 111 g per 100 mL at 20°C.
  • Cation Interaction: The solubility can be attributed to the strong interaction between the potassium ions (K+) and hydroxide ions (OH-), which facilitates dissolution.
  • Temperature Effects: Increasing temperature typically enhances the solubility of KOH, making it an important factor in its use in various chemical processes.
  • Acid-Base Reactions: When dissolved, KOH readily dissociates, providing hydroxide ions that can react with acids, showcasing its efficacy in neutralization reactions.

As a result, potassium hydroxide's ability to dissolve in water makes it a critical component in various industrial applications, particularly in the production of soaps, detergents, and fertilizers.

In summary, "The more KOH is dissolved, the more potent its basicity becomes."

Interesting facts

Interesting Facts about Potassium Hydroxide

Potassium hydroxide, often referred to as caustic potash, is an intriguing chemical compound with a variety of applications in both industrial and laboratory settings. Here are some compelling points that highlight its significance:

  • Versatile Uses: Potassium hydroxide is widely used in fertilizers, soap making, and as a strong alkaline agent in various chemical reactions.
  • Alkalinity: It is one of the strongest bases available, which makes it crucial for pH regulation in numerous chemical processes.
  • Hydration Reaction: When potassium hydroxide dissolves in water, it releases a significant amount of heat—a phenomenon known as an exothermic reaction.
  • Food Industry Application: In food processing, potassium hydroxide is sometimes utilized for peeling fruits and vegetables, highlighting its role beyond traditional chemistry.
  • Safety Considerations: As a highly caustic substance, safety precautions are essential when handling potassium hydroxide to avoid burns and skin irritation.

In the words of renowned chemist Linus Pauling, “The best way to have a good idea is to have lots of ideas.” Similarly, potassium hydroxide embodies numerous ideas and applications, making it a cornerstone in many scientific and industrial fields.

With its fascinating properties and diverse uses, potassium hydroxide remains a compound of great interest to chemists and industry professionals alike, showcasing the interplay of chemistry in practical applications.

Synonyms
POTASSIUM HYDROXIDE
1310-58-3
Caustic potash
Potash lye
Potassium hydrate
Hydroxyde de potassium
Potassa
Potasse caustique
Caustic-potash
Kali causticum
Caswell No. 693
Cyantek CC 723
Kaliumhydroxid
Aetzkali
CCRIS 6569
Potassio (idrossido di)
HSDB 1234
Potassium (hydroxyde de)
UNII-WZH3C48M4T
EINECS 215-181-3
WZH3C48M4T
EPA Pesticide Chemical Code 075602
INS NO.525
CHEBI:32035
INS-525
DTXSID5029633
E-525
EC 215-181-3
KOH
POTASSIUM HYDROXIDE (II)
POTASSIUM HYDROXIDE [II]
POTASSIUM HYDROXIDE (MART.)
POTASSIUM HYDROXIDE [MART.]
POTASSIUM HYDROXIDE (EP MONOGRAPH)
POTASSIUM HYDROXIDE [EP MONOGRAPH]
Kaliumhydroxyde
Atzkali
Potassium lye
potasio hidroxido
MIRACLE WATER 3 in 1
DTXCID209633
215-181-3
potassium hydroxide (acgih)
Potassium hydroxide (K(OH))
potassium;hydroxide
MFCD00003553
Potassium hydroxide, pellets
Potassium hydroxide, flake
Potassium Hydroxide (~85%)
potassiumhydroxide
Potasse caustique [French]
Potassium hydroxide [JAN]
Potassium Hydroxide (Semiconductor Grade)
Hydroxyde de potassium [French]
Potassio (idrossido di) [Italian]
Potassium (hydroxyde de) [French]
UN1813
UN1814
Kalilauge
Potassium hydroxide [JAN:NF]
hydroxyl potassium
potasium hydroxide
potassium hydoxide
potassium hydroxid
potassium hyroxide
potassium hydorxide
Acid Number Standard 0.1 mgKOH/g. Reference materials intended for use in the determination of Acid
Acid Number Standard 0.5 mgKOH/g. Reference materials intended for use in the determination of Acid
Acid Number Standard 1 mgKOH/g. Reference materials intended for use in the determination of Acid Nu
Acid Number Standard 3 mgKOH/g. Reference materials intended for use in the determination of Acid Nu
Base Number Standard 10 mgKOH/g. Reference material intended for use in the determination of Base Nu
Base Number Standard 30 mgKOH/g. Reference materials intended for use in the determination of Base N
Base Number Standard 6 mgKOH/g. Reference materials intended for use in the determination of Base Nu
potassium -hydroxide
Potassium hydroxide (TN)
Potassium hydroxide, solid
Potassium hydroxide (KOH)
Potassium Hydroxide, flakes
Potassium hydroxide anhydrous
Potassium Hydroxide (Powder)
KALI CAUSTICUM [HPUS]
Potassium Hydroxide (Pellets)
Potassium hydroxide on alumina
CHEMBL2103983
POTASSIUM HYDROXIDE [MI]
Potassium hydroxide (JP17/NF)
POTASSIUM HYDROXIDE [FCC]
Potassium Hydroxide, powder, ACS
POTASSIUM HYDROXIDE [HSDB]
Potassium hydroxide, p.a., 85%
POTASSIUM HYDROXIDE [VANDF]
POTASSIUM HYDROXIDE [WHO-DD]
AKOS015904616
DB11153
FP34861
Potassium hydroxide, pellet, ACS reagent
Potassium hydroxide, pellets, ACS reagent
Potassium hydroxide, AR, flakes, >=85%
Potassium hydroxide, LR, flakes, >=85%
Potassium hydroxide, technical grade, 80%
Potassium hydroxide, AR, pellets, >=85%
Potassium hydroxide, LR, pellets, >=85%
NS00081389
P2844
P2849
D01168
Potassium hydroxide, technical, >=85%, lumps
Potassium hydroxide, technical, >=85%, powder
Potassium hydroxide, BioXtra, >=85% KOH basis
Potassium hydroxide, reagent grade, 90%, flakes
Potassium hydroxide, SAJ first grade, >=85.0%
Potassium hydroxide, tested according to Ph.Eur.
Potassium hydroxide, JIS special grade, >=85.0%
Potassium hydroxide, ROTI?Volum, 0,1N (Ampoule)
Q132298
Potassium hydroxide, ACS reagent, >=85%, pellets
Potassium hydroxide, electronic grade, 50% in H2O
Potassium hydroxide, solid [UN1813] [Corrosive]
Potassium hydroxide solution 10% (wt/v) in methanol
Potassium hydroxide, >=85% KOH basis, pellets, white
Base Number (BN) Standard: 6 mg KOH/g in Hydrocarbon Oil
Potassium hydroxide, pellets, Trace Metals Grade 99.95%
Potassium hydroxide, puriss. p.a., >=86% (T), pellets
Acid Number (AN) Standard: 0.1 mg KOH/g in Hydrocarbon Oil
Acid Number (AN) Standard: 0.5 mg KOH/g in Hydrocarbon Oil
Acid Number (AN) Standard: 1.0 mg KOH/g in Hydrocarbon Oil
Acid Number (AN) Standard: 1.5 mg KOH/g in Hydrocarbon Oil
Acid Number (AN) Standard: 2.0 mg KOH/g in Hydrocarbon Oil
Acid Number (AN) Standard: 3.0 mg KOH/g in Hydrocarbon Oil
Base Number (BN) Standard: 10 mg KOH/g in Hydrocarbon Oil
Base Number (BN) Standard: 15 mg KOH/g in Hydrocarbon Oil
Base Number (BN) Standard: 30 mg KOH/g in Hydrocarbon Oil
Base Number (BN) Standard: 40 mg KOH/g in Hydrocarbon Oil
Base Number (BN) Standard: 70 mg KOH/g in Hydrocarbon Oil
Potassium hydroxide, anhydrous, >=99.97% trace metals basis
Potassium hydroxide, puriss. p.a., Reag. Ph. Eur., >=85%, pellets
Potassium hydroxide, semiconductor grade PURANAL(TM) (Honeywell 17851)
Potassium hydroxide solution in ethanol, 0,05 mol/l, 0,05 N volumetric standard solution
Acid Number Standard 1.5 mgKOH/g. Reference materials intended for use in the determination of Acid Number in petroleum products by potentiometric titration (ASTM D664) or color-indicator titration
Acid Number Standard 2 mgKOH/g. Reference materials intended for use in the determination of Acid Nu
Potassium hydroxide, puriss., meets analytical specification of Ph. Eur., BP, NF, 85-100.5%, pellets
Potassium hydroxide, semiconductor grade, pellets, 99.99% trace metals basis (Purity excludes sodium content.)