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Triethylstannanylium Sulfide

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Identification
Molecular formula
C6H15SSn
CAS number
2921-28-8
IUPAC name
sulfanide;triethylstannane;triethylstannanylium
State
State

At room temperature, triethylstannanylium sulfide is a solid.

Melting point (Celsius)
53.00
Melting point (Kelvin)
326.15
Boiling point (Celsius)
112.00
Boiling point (Kelvin)
385.15
General information
Molecular weight
382.11g/mol
Molar mass
382.1100g/mol
Density
1.2225g/cm3
Appearence

Triethylstannanylium sulfide is typically a colorless to yellowish crystalline solid. Its crystalline structure results in a distinct shiny appearance.

Comment on solubility

Solubility of Sulfanide and Triethylstannane

When discussing the solubility of triethylstannane (also known as triethylstannanylium), it is crucial to consider its organic and inorganic components. Generally, triethylstannane is a hydrophobic compound which exhibits limited solubility in water due to its hydrocarbon chains. However, it shows better solubility in organic solvents.

Factors Affecting Solubility

Several factors affect the solubility of these compounds:

  • Polarity: Organic compounds like triethylstannane are non-polar, lending them poor solubility in polar solvents like water.
  • Temperature: Increasing temperature can enhance solubility for some solvents, impacting the dissolution process.
  • Nature of Solvent: Solvents such as hexane, ether, or chloroform often dissolve triethylstannane effectively due to their non-polar nature.

It is important to note that triethylstannanylium might have unique solubility properties due to its ionic character. Such compounds can exhibit greater solubility in polar environments compared to their neutral counterparts. As the chemistry continues to evolve, the understanding and manipulation of these solubility characteristics provide valuable insights into their applications in synthetic pathways.

In essence, while triethylstannane and its derivative triethylstannanylium are less soluble in water, they remain versatile in a variety of organic solutions, enabling their use in different chemical reactions and applications.

Interesting facts

Interesting Facts About Triethylstannane

Triethylstannane, also known by its IUPAC name, triethylstannium, is a fascinating organometallic compound featuring tin as its central atom. Below are some notable aspects of this compound:

  • Organometallic Chemistry: Triethylstannane belongs to a class of compounds that contain a carbon-to-metal bond, which places it squarely in the realm of organometallic chemistry. These compounds often play significant roles in catalysis and materials science.
  • Stability and Reactivity: Triethylstannane is relatively stable under normal conditions but can react with electrophiles. This makes it valuable in synthetic organic chemistry for various transformations.
  • Applications in Synthesis: It serves as a versatile reagent in the synthesis of a variety of organic compounds. For instance, it is particularly useful in nucleophilic substitutions due to the presence of the tin atom.

Unique Properties and Behaviors

Aside from its practical applications, triethylstannane showcases unique properties:

  • Substituent Effects: The ethyl groups surrounding the tin atom influence the electronic properties of the compound, enhancing its nucleophilicity.
  • Stannylation Reactions: This compound is often employed in stannylation, a process wherein a stannane group is introduced into a substrate. It can significantly alter the reactivity and properties of the substrate.

In the words of renowned chemist Linus Pauling, “Chemistry is the study of symmetry.” Triethylstannane exemplifies this balance between metallic and organic characteristics, showcasing how diverse and intricate chemical compounds can be.

In summary, triethylstannane is not just a simple compound; it is a gateway to understanding more complex reactions and applications in modern chemistry.