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Triammonium hexafluoroferrate(III)

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Identification
Molecular formula
(NH4)3FeF6
CAS number
20034-11-9
IUPAC name
triammonium;hexafluoroiron(3-)
State
State

At room temperature, triammonium hexafluoroferrate(III) is a solid. It typically comes in a crystalline powder form and remains stable under regular conditions.

Melting point (Celsius)
200.00
Melting point (Kelvin)
473.00
Boiling point (Celsius)
150.00
Boiling point (Kelvin)
423.00
General information
Molecular weight
229.08g/mol
Molar mass
229.0800g/mol
Density
0.8500g/cm3
Appearence

Triammonium hexafluoroferrate(III) appears as a yellow crystalline solid. It can form needle-like crystals and has a bright and distinct yellow color that is characteristic of many iron(III) complexes.

Comment on solubility

Solubility of Triammonium Hexafluoroiron(III)

The solubility of triammonium hexafluoroiron(III), with the formula (NH4)3FeF6, is influenced by several factors:

  • Water Solubility: Triammonium hexafluoroiron(III) is generally considered to be soluble in water due to the presence of the ammonium ion (NH4+), which is known for its solubility.
  • Ionic Nature: Being an ionic compound, the interaction between the compound and water molecules facilitates dissolution. The hexafluoroanion (FeF63-) also contributes to its solubility due to its ability to stabilize in an aqueous environment.

However, there are some important considerations:

  • Temperature Dependence: The solubility can vary with temperature; it may increase at higher temperatures.
  • Concentration Effects: In highly concentrated solutions, the solubility limit can be reached, leading to precipitation.
  • pH Sensitivity: The solubility may also be affected by the pH of the solution, with potential changes in solubility in acidic or basic conditions.

To summarize, "triammonium hexafluoroiron(III)" demonstrates notable solubility characteristics primarily due to its ionic nature and the stabilizing effects of the constituent ions in aqueous media. It serves as a suitable example of an ionic compound that effectively dissolves, exhibiting the principles of solvation and ionic interactions.

Interesting facts

Interesting Facts about Triammonium Hexafluoroiron(III)

Triummonium hexafluoroiron(III) is a fascinating compound that showcases the interplay between ammonia, a simple nitrogen-based molecule, and iron, a transition metal known for its diverse oxidation states and catalytic properties. Here are some intriguing aspects of this compound:

  • Composition: This compound consists of three ammonium ions (NH₄+) combined with a hexafluoroiron(III) ion (FeF₆3-). This unique composition results in a strongly ionic character, providing insights into coordination chemistry.
  • Oxidation State: The iron in this compound is in the +3 oxidation state, which is significant in many biological and industrial processes. Iron(III) often participates in redox reactions, making this compound interesting for studies in electron transfer.
  • Coordination Chemistry: The hexafluoro complex is notable for its octahedral geometry, a common arrangement that enhances the understanding of ligand field theory and the behavior of transition metals in solution.
  • Applications: Compounds like triammonium hexafluoroiron(III) are utilized in various applications, including catalysis, materials science, and as precursors in the synthesis of other complex compounds. Their unique properties may also lead to applications in magnetic materials.
  • Stability: The presence of fluorine atoms contributes to the stability of the iron complex, which may influence the reactivity of the compound in various chemical reactions, making it an excellent candidate for kinetic studies.
  • Chemical Synthesis: The synthesis of this compound often involves the reaction of ammonium salts with iron(III) fluoride, highlighting the fascinating transformations that occur in coordination complexes.

This compound stands as an exemplary model for students and researchers delving into the world of inorganic chemistry. Its complex structure not only piques scientific curiosity but also embodies the principles of coordination chemistry.

Synonyms
Ammonium hexafluoroferrate
13815-28-6
Triammonium hexafluoroferrate(3-)
Ammonium fluoroferrate(III)
Ammonium hexafluoroferrate(III)
Ferrate(3-), hexafluoro-, triammonium, (OC-6-11)-
Ammonium hexafluoroferrate(III) (7CI)
FERRATE(3-), HEXAFLUORO-, TRIAMMONIUM SALT
SCHEMBL775304
DTXSID70160504