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Tridecane-1-thiol

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Identification
Molecular formula
C13H28S
CAS number
26896-22-2
IUPAC name
tridecane-1-thiol
State
State
Tridecane-1-thiol is a liquid at room temperature.
Melting point (Celsius)
-49.00
Melting point (Kelvin)
224.15
Boiling point (Celsius)
265.00
Boiling point (Kelvin)
538.15
General information
Molecular weight
216.43g/mol
Molar mass
216.4140g/mol
Density
0.8453g/cm3
Appearence

Tridecane-1-thiol is a clear, colorless liquid. It is known for its characteristic "thiol" smell, which can be quite pungent and strong.

Comment on solubility

Solubility of Tridecane-1-thiol

Tridecane-1-thiol, with the chemical formula C13H28S, is a member of the thiol family characterized by the presence of a sulfhydryl (-SH) group. When analyzing the solubility of tridecane-1-thiol, several important factors need to be considered:

  • Hydrophobic Character: Due to its long hydrocarbon chain, tridecane-1-thiol is primarily hydrophobic, which makes it less soluble in polar solvents such as water.
  • Solubility in Organic Solvents: It shows good solubility in organic solvents like:
    • Hexane
    • Octanol
    • Toluene
  • Influence of Chain Length: As a long-chain thiol, the solubility characteristics vary slightly from shorter chain counterparts, typically being less soluble in water as chain length increases.
  • Temperature Effects: Solubility can also be influenced by temperature; with an increase in temperature, the solubility of tridecane-1-thiol in organic solvents may improve due to enhanced molecular movement.

In summary, tridecane-1-thiol exhibits limited solubility in water, making it more suitable for applications in non-polar environments. This behavior is consistent with other thiols possessing long hydrocarbon chains, reinforcing the significance of molecular structure on solubility.

Interesting facts

Exploring Tridecane-1-thiol

Tridecane-1-thiol is a fascinating compound that belongs to the class of thiols, or mercaptans, which are characterized by the presence of a sulfur atom. This compound is composed of a long carbon chain, specifically comprising thirteen carbon atoms, with a thiol functional group (-SH) attached at one end. Here are some intriguing aspects of tridecane-1-thiol:

  • Odor and Aroma: Thiols are known for their distinctive and often unpleasant odors. Tridecane-1-thiol, for example, can emit a strong smell reminiscent of rotten cabbage, making it a compound of interest in studies related to olfaction.
  • Natural Occurrence: Compounds like tridecane-1-thiol can be found in some natural contexts, including certain biological processes and the degradation of organic material, which might explain their potent odor.
  • Applications in Research: This compound plays a significant role in the field of organic chemistry and materials science. Researchers may utilize it in the synthesis of more complex molecules or in the development of new materials.
  • Safety Concerns: Due to its strong odor, handling tridecane-1-thiol requires caution. It is important to work with it in well-ventilated areas and to wear appropriate protective gear.

Furthermore, tridecane-1-thiol is an example of how even simple molecules can have complex and far-reaching implications in both chemistry and nature. It's a reminder of the intricate web of reactions and interactions that exist in the chemical world.

As a chemist or a student, diving into the study of compounds like tridecane-1-thiol opens up a world of exploration and understanding about the unique properties of sulfur compounds and their applications. “The beauty of chemistry lies in its ability to connect the molecular with the macroscopic,” they often say, and tridecane-1-thiol illustrates this principle beautifully.

Synonyms
1-TRIDECANETHIOL
tridecane-1-thiol
19484-26-5
Tridecyl mercaptan
TRIDECYL THIOL
NSC 851
NSC-851
YW32XX0340
EINECS 243-104-3
1-MERCAPTOTRIDECANE
DTXSID8066501
DTXCID3036107
RefChem:436856
Tridecanethiol
UNII-YW32XX0340
NSC851
1-TRIDECANTHIOL
SCHEMBL132801
SCHEMBL132802
SCHEMBL2794610
SCHEMBL5063700
SCHEMBL9682258
SCHEMBL20473142
UAA48426
NS00026354
Q27294742